Ruthenium-promoted Z-selective head-to-head dimerization of terminal alkynes in organic and aqueous media

被引：74

作者：

Chen, XG

Xue, P

Sung, HHY

Williams, ID

Peruzzini, M

Bianchini, C

Jia, GC

机构：

[1] CNR, Ist Chim Composti Organomet, I-50019 Florence, Italy

[2] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 18期

关键词：

D O I：

10.1021/om050355x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[RuH(CH3CN)(NP3)]OTf effectively catalyzes the dimerization of both aliphatic and aromatic alkynes to give (Z)-enynes in high regio- and stereoselectivity. The catalytic system can tolerate a number of functional groups, which allows for its use in organic and aqueous medium.

引用

收藏

页码：4330 / 4332

页数：3

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