Enzymatic resolution of p-amino methyl esters using lipase B from Candida antarctica

被引：0

作者：

Escalante, Jaime ^{[1
]}

机构：

[1] UAEM, Ctr Invest Quim, Cuernavaca 62210, Morelos, Mexico

来源：

RECENT DEVELOPMENTS IN PHYSICAL CHEMISTRY | 2008年 / 979卷

关键词：

enzymatic catalysis; Cal-B; beta-amino acids; CATALYZED MICHAEL ADDITION; ORGANIC MEDIA; ACID; HYDROLYSIS; ALCOHOLS;

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report the enzymatic resolution of methyl 3-aminobutanoate and methyl 3-amino-3-phenylpropanoate derivatives, with the amine protected with groups such as Bz, Cbz, Boc, Fmoc and aminobenzamide (ABA). The resolutions were carried out through transesterifications catalyzed by lipase B from Candida antarctica (Cal-B). The reactions proceeded with a high conversion and yielded optically pure enantiomers.

引用

页码：60 / 67

页数：8

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