Ionic liquids to the rescue? Overcoming the ionic conductivity limitations of polymer electrolytes

被引：432
|
作者：
Shin, JH [1 ]
Henderson, WA [1 ]
Passerini, S [1 ]
机构：
[1] ENEA, IDROCOMB, Casaccia Res Ctr, Italian Natl Agcy New Technol, I-00060 Rome, Italy
来源：
ELECTROCHEMISTRY COMMUNICATIONS | 2003年 / 5卷 / 12期
基金：
美国国家科学基金会;
关键词：
polymer electrolyte; ionic liquid; lithium batteries; ionic conductivity; LiTFSI;
D O I：
10.1016/j.elecom.2003.09.017
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Polymer electrolytes - solid polymeric membranes with dissolved salts - are being intensively studied for use in all-solid-state lithium-metal-polymer (LMP) batteries to power consumer electronic devices. The low ionic conductivity at room temperature of existing polymer electrolytes, however, has seriously hindered the development of such batteries for many applications. The incorporation of salts molten at room temperature (room temperature ionic liquids or RTILs) into polymer electrolytes may be the necessary solution to overcoming the inherent ionic conductivity limitations of 'dry' polymer electrolytes. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码：1016 / 1020
页数：5
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