3D printing of CNT-and graphene-based conductive polymer nanocomposites by fused deposition modeling

被引:445
作者
Gnanasekaran, K. [1 ]
Heijmans, T. [1 ]
van Bennekom, S. [2 ]
Woldhuis, H. [2 ]
Wijnia, S. [2 ]
de With, G. [1 ]
Friedrich, H. [1 ]
机构
[1] Eindhoven Univ Technol, Lab Mat & Interface Chem, Eindhoven, Netherlands
[2] Ultimaker BV, Geldermalsen, Saudi Arabia
关键词
3D printing; Fused deposition modeling; Polymer nanocomposites; CNT; Graphene; Nozzle wear; PERCOLATION; PERFORMANCE; TOMOGRAPHY; COMPOSITES;
D O I
10.1016/j.apmt.2017.04.003
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Fused deposition modeling (FDM) is limited by the availability of application specific functional materials. Here we illustrate printing of non-conventional polymer nanocomposites (CNT- and graphene-based polybutylene terephthalate (PBT)) on a commercially available desktop 3D printer leading toward printing of electrically conductive structures. The printability, electrical conductivity and mechanical stability of the polymer nanocomposites before and after 3D printing was evaluated. The results show that 3D printed PBT/CNT objects have better conductive and mechanical properties and a better performance than 3D printed PBT/graphene structures. In addition to that, printing more than one material (multi materials) and challenges in using abrasive conductive fillers (i.e., CNT and graphene) are also discussed. Overall this study demonstrates that a commercially available desktop 3D printer can be used to fabricate low-cost functional objects. (C) 2017 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license
引用
收藏
页码:21 / 28
页数:8
相关论文
共 45 条
[1]   Electrical conductivity recovery in carbon nanotube polymer composites after transient shear [J].
Alig, I. ;
Skipa, T. ;
Engel, M. ;
Lellinger, D. ;
Pegel, S. ;
Poetschke, P. .
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2007, 244 (11) :4223-4226
[2]   Helical 3D-Printed Metal Electrodes as Custom-Shaped 3D Platform for Electrochemical Devices [J].
Ambrosi, Adriano ;
Moo, James Guo Sheng ;
Pumera, Martin .
ADVANCED FUNCTIONAL MATERIALS, 2016, 26 (05) :698-703
[3]   A simple and flexible route to large-area conductive transparent graphene thin-films [J].
Arapov, Kirill ;
Goryachev, Andrey ;
de With, Gijsbertus ;
Friedrich, Heiner .
SYNTHETIC METALS, 2015, 201 :67-75
[4]   Electrical properties and applications of carbon nanotube structures [J].
Bandaru, Prabhakar R. .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2007, 7 (4-5) :1239-1267
[5]  
Bellehtuneur C., 2001, J MANUF PROCESS, V6, P170
[6]   Comparison of tribological behaviour for Nylon6-Al-Al2O3 and ABS parts fabricated by fused deposition modelling This paper reports a low cost composite material that is more wear-resistant than conventional ABS [J].
Boparai, Kamaljit ;
Singh, Rupinder ;
Singh, Harwinder .
VIRTUAL AND PHYSICAL PROTOTYPING, 2015, 10 (02) :59-66
[7]   Hierarchical polymer-nanotube composites [J].
Chatterjee, Tirtha ;
Mitchell, Cynthia A. ;
Hadjiev, Viktor G. ;
Krishnamoorti, Ramanan .
ADVANCED MATERIALS, 2007, 19 (22) :3850-+
[8]  
Chua CK, 2015, 3D PRINTING AND ADDITIVE MANUFACTURING: PRINCIPLES AND APPLICATIONS, THE 4TH EDITION OF RAPID PROTOTYPING: PRINCIPLES AND APPLICATIONS, DOI 10.1142/9008
[9]   Reinforcement mechanisms in MWCNT-filled polycarbonate [J].
Eitan, A. ;
Fisher, F. T. ;
Andrews, R. ;
Brinson, L. C. ;
Schadler, L. S. .
COMPOSITES SCIENCE AND TECHNOLOGY, 2006, 66 (09) :1162-1173
[10]   Experimental investigations on fused deposition modelling of polymer-layered silicate nanocomposite [J].
Francis, Vishal ;
Jain, Prashant K. .
VIRTUAL AND PHYSICAL PROTOTYPING, 2016, 11 (02) :109-121