Temperature dependence of photoluminescence and magnetic properties in Yb3+-doped ZnS nanocrystals

被引:5
作者
Ye, Xiaoliang [1 ]
Mao, Huibing [1 ]
Hou, Shili [1 ]
Wang, Jiqing [1 ]
机构
[1] E China Normal Univ, Dept Elect Engn, Shanghai 200241, Peoples R China
关键词
ZnS; XRD; Nanocrystals; Photoluminescence; OPTICAL-PROPERTIES; FLUORESCENCE; IONS; LUMINESCENCE;
D O I
10.1016/j.physb.2011.05.050
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Zinc sulfide semiconductor nanocrystals doped with Yb3+ ions have been prepared through a chemical precipitation method using PVP (polyvinylpyrrolidone) as a capping agent. The structure of the nanoparticles has been analyzed by X-ray diffraction (XRD). The average size of the nanoparticles is found to be 3.7 +/- 0.4 nm. Photoluminescence spectra were recorded for doped ZnS nanoparticles as a function of temperature between 9 and 300 K. The results suggest that two emission bands have been observed at different temperatures. The width of 1.269 eV peak increases as temperature is raised. A shift of lower energy emission band has been observed with the change of temperature. Moreover, the magnetic measurement showed that the sample exhibits paramagnetic behavior. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:3318 / 3321
页数:4
相关论文
共 26 条
[1]   VISIBLE FLUORESCENCE OF ER3+ IN YTTRIUM GALLIUM GARNET [J].
CHAMBERLAIN, JR ;
PAXMAN, DH ;
PAGE, JL .
PROCEEDINGS OF THE PHYSICAL SOCIETY OF LONDON, 1966, 89 (563P) :143-+
[2]   Upconversion luminescence of Eu3+ and Mn2+ in ZnS:Mn2+, Eu3+ codoped nanoparticles [J].
Chen, W ;
Joly, AG ;
Malm, JO ;
Bovin, JO .
JOURNAL OF APPLIED PHYSICS, 2004, 95 (02) :667-672
[3]   Energy structure and fluorescence of Eu2+ in ZnS:Eu nanoparticles [J].
Chen, W ;
Malm, JO ;
Zwiller, V ;
Huang, YN ;
Liu, SM ;
Wallenberg, R ;
Bovin, JO ;
Samuelson, L .
PHYSICAL REVIEW B, 2000, 61 (16) :11021-11024
[4]  
Cheng G.F., 2008, J INORG MATER, V23, P200
[5]  
Ding L.H., 2008, CHIN J LUMIN, V29, P5
[6]  
Dong X.T., 2001, RARE METAL MAT ENG, V30, P1
[7]   Synthesis and photoluminescence properties of ZnMnS nanobelts [J].
Geng, BY ;
Zhang, LD ;
Wang, GZ ;
Xie, T ;
Zhang, YG ;
Meng, GW .
APPLIED PHYSICS LETTERS, 2004, 84 (12) :2157-2159
[8]  
Guo Z.B., 2008, CHIN J LOW TEMP PHYS, V30, P87
[9]   Photoluminescence and XPS investigations of Cu2+-doped ZnS quantum dots capped with polyvinylpyrrolidone [J].
Hou, Shili ;
Zhang, Xiangqiang ;
Mao, Huibing ;
Wang, Jiqing ;
Zhu, Ziqiang ;
Jing, Weiping .
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2009, 246 (10) :2333-2336
[10]  
Huang K., 2005, PROG PHYS, V1, P32