Energy transfer in pendant perylene diimide copolymers

被引：29

作者：

Davis, Nathaniel J. L. K. ^{[1
]}

MacQueen, Rowan W. ^{[2
]}

Roberts, Derrick A. ^{[3
]}

Danos, Andrew ^{[2
]}

Dehn, Sabrina ^{[4
]}

Perrier, Sebastien ^{[5
,6
]}

Schmidt, Timothy W. ^{[2
]}

机构：

[1] Univ Cambridge, Cavendish Lab, JJ Thomson Ave, Cambridge CB3 0HE, England

[2] UNSW Sydney, Sch Chem, Sydney, NSW 2052, Australia

[3] Dept Chem, Lensfield Rd, Cambridge CB2 1EW, England

[4] Univ Sydney, Key Ctr Polymers & Colloids, Sch Chem, Sydney, NSW 2006, Australia

[5] Univ Warwick, Dept Chem, Gibbet Hill Rd, Coventry CV4 7AL, W Midlands, England

[6] Monash Univ, Fac Pharm & Pharmaceut Sci, 381 Royal Parade, Parkville, Vic 3052, Australia

来源：

JOURNAL OF MATERIALS CHEMISTRY C | 2016年 / 4卷 / 35期

基金：

澳大利亚研究理事会;

关键词：

LUMINESCENT SOLAR CONCENTRATORS; QUANTUM YIELDS; THIN-FILMS; DYES; FLUORESCENCE; EFFICIENT; PHOTOPHYSICS; PERFORMANCE;

D O I：

10.1039/c6tc02555b

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We report the synthesis, characterisation and polymerisation of two novel asymmetric perylene diimide acrylate monomers. The novel monomers form a sensitiser-acceptor pair capable of undergoing Forster resonance energy transfer, and were incorporated as copolymers with tert-butyl acrylate. The tert-butyl acrylate units act as spacers along the polymer chain allowing high concentrations of dye while mitigating aggregate quenching, leading to persistent fluorescence in the solid state at high concentrations of up to 0.3 M. Analysis of fluorescence kinetics showed efficient energy transfer between the optically dense sensitiser and the lower concentration acceptor luminophores within the polymer. This reduced reabsorption within the material demonstrates that the copolymer-scaffold energy transfer system has potential for use in luminescent solar concentrators.

引用

页码：8270 / 8275

页数：6

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