Recent advances in lanthanide coordination polymers and clusters with magnetocaloric effect or single-molecule magnet behavior

被引:36
作者
Hu, Jun-Jie [1 ]
Peng, Yan [1 ]
Liu, Sui-Jun [1 ]
Wen, He-Rui [1 ]
机构
[1] Jiangxi Univ Sci & Technol, Sch Chem & Chem Engn, Ganzhou 341000, Jiangxi, Peoples R China
基金
中国国家自然科学基金;
关键词
METAL-ORGANIC FRAMEWORK; GD-III COMPLEXES; LIGAND SUBSTITUTION; ANISOTROPY BARRIER; HIGH-SPIN; MAGNETOTHERMAL PROPERTIES; MAGNETIZATION RELAXATION; NI-II; ION; EXCHANGE;
D O I
10.1039/d1dt02797b
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Molecular magnetorefrigerant materials for low-temperature magnetic refrigeration and single-molecule magnets for high-density information storage and quantum computing have received extensive attention from chemists and magnetic experts. Lanthanide ions with unique magnetic properties have always been considered as ideal candidates for the construction of such materials. This frontier article focuses on Gd-III-based molecular magnetorefrigerants and lanthanide-based single-molecule magnets and highlights the most significant advances.
引用
收藏
页码:15473 / 15487
页数:15
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