Novel imidazolination reaction of alkenes provides an easy access to new α,β-differentiated 1,2-vicinal diamines

被引：28

作者：

Pei, W ^{[1
]}

Timmons, C ^{[1
]}

Xu, X ^{[1
]}

Wei, HX ^{[1
]}

Li, GG ^{[1
]}

机构：

[1] Texas Tech Univ, Dept Chem & Biochem, Lubbock, TX 79409 USA

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2003年 / 1卷 / 16期

关键词：

D O I：

10.1039/b305149h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

alpha,beta-Differentiated 1,2-vicinal diamines have been efficiently synthesized by using new electrophilic imidazolination reaction of alkenes. The hydrolysis of imidazolines was performed by treatment with 6 M HCl in THF at 70 degreesC without epimerization. Eight examples were examined to give good to excellent yields (87-96%).

引用

页码：2919 / 2921

页数：3

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