Pyrolysis of agricultural residues for bio-oil production

被引:52
作者
Alper, Koray [1 ,2 ]
Tekin, Kubilay [3 ]
Karagoz, Selhan [4 ]
机构
[1] Karabuk Univ, Dept Chem, TR-78050 Karabuk, Turkey
[2] Bulent Ecevit Univ, Sci & Technol Res Ctr, TR-67600 Zonguldak, Turkey
[3] Karabuk Univ, Dept Occupat Hlth & Safety, TR-78050 Karabuk, Turkey
[4] Karabuk Univ, Dept Polymer Engn, TR-78050 Karabuk, Turkey
关键词
Pyrolysis; Cornelian cherry stone; Grape seeds; Bio-oil; Bio-char; CATALYTIC PYROLYSIS; SEED CAKE; BIOMASS; TEMPERATURE; LIQUID; CONVERSION; FRACTION; BEHAVIOR;
D O I
10.1007/s10098-014-0778-8
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The production of biofuel from biomass waste is of great interest to the scientific community regarding the discovery of solutions to global energy demand and global warming. The pyrolysis of biomass to produce bio-oil is an easy, cheap and promising technology. In the current investigation, the pyrolysis of two different biomasses (cornelian cherry stones and grape seeds) was achieved at temperatures ranging from 300 to 700 A degrees C. The effect of pyrolysis temperatures on the yields of each product was significant. The bio-oil yields were maximized at 500 A degrees C for cornelian cherry stones and 700 A degrees C for grape seeds. The compositions of bio-oils for both cornelian cherry stones and grape seeds were similar and contained mainly oxygenated hydrocarbons. The compounds observed in this investigation were composed of phenols, alkyl benzenes, alkanes, alkenes, fatty acids, fatty acid esters and a few nitrogen-containing compounds. Bio-char properties were amended in association with both the pyrolysis temperature and biomass type. Bio-chars from cornelian cherry stones contained higher carbon and lower oxygen levels than those from grape seeds under identical conditions. Increases in pyrolysis temperatures produced bio-chars containing higher carbon levels and heating values for both carnelian cherry stones and grape seeds.
引用
收藏
页码:211 / 223
页数:13
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