Improving the flame retardancy and electrical conductivity of epoxy resin composites by multifunctional phosphorus-containing polyaniline

被引:14
作者
Zhan, Zhaoshun [1 ]
Zhang, Yaolong [1 ]
Zhang, Yue [1 ]
机构
[1] Heilongjiang Univ Sci & Technol, Coll Environm & Chem Engn, Harbin 150022, Peoples R China
关键词
Flame retardancy; Electrical conductivity; Epoxy resin; Polyaniline; Polymeric composites; Thermal analysis; HYBRID; PERFORMANCE;
D O I
10.1016/j.matlet.2019.127092
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Condensation polymerization was used to prepare phosphorus-containing polyaniline (FR-PANI) constructed with conjugative structure whose chemical constitution, morphology and volume resistivity were studied in this work. After being combined with epoxy resin (EP) (denoted as EP/FR-PANI or EP/PANI), the composite's electrical conductivity, flame retardancy and thermal stability were evaluated. The volume resistivity of the EP composite was reduced by importing the FR-PANI. The limiting oxygen index values reached 30.8% for the EP/4 wt% FR-PANI composite and obtained a V-0 rating in the vertical burning test. The thermal stability of the EP composite was improved by increasing the char yield for pure EP from 14.6 to 20.1%. (C) 2019 Elsevier B.V. All rights reserved.
引用
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页数:5
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