Optimization of electrochemical treatment of industrial paint wastewater with response surface methodology

被引:157
作者
Koerbahti, Bahadir K.
Aktas, Nahit
Tanyolac, Abdurrahman [1 ]
机构
[1] Hacettepe Univ, Dept Chem Engn, Fac Engn, TR-06800 Ankara, Turkey
[2] Univ Mersin, Dept Chem Engn, Fac Engn, TR-33343 Ciftlikkoy, Mersin, Turkey
[3] Yuzuncu Yil Univ, Dept Chem Engn, Engn & Architecture Fac, TR-65080 Van, Turkey
关键词
electrochemical wastewater treatment; paint wastewater; graphite electrodes; statistical experiment design; response surface methodology; NaCl electrolyte;
D O I
10.1016/j.jhazmat.2007.02.005
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The electrochemical oxidation of water-based paint wastewater was investigated batch-wise in the presence of NaCl electrolyte with carbon electrodes for the first time in literature. The electrochemical treatment conditions were optimized using response surface methodology where potential difference, reaction temperature and electrolyte concentration were to be minimized while chemical oxygen demand (COD), color and turbidity removal percents and initial COD removal rate were maximized at 100% pollution load. The optimum conditions were satisfied at 35 g/L external electrolyte concentration, 30 degrees C reaction temperature and 8 V potential difference (64.37 mA/cm(2) current density) realizing 51.8% COD and complete color and turbidity removals, and 3010.74 mg/L h initial COD removal rate. According to these results, the electrochemical method could be a strong alterative to conventional physicochemical methods for the treatment of water-based paint wastewater. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:83 / 90
页数:8
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