Density, viscosity and electrical conductivity of AlCl3-amide ionic liquid analogues

被引：40

作者：

Liu, Chengyuan ^{[1
]}

Chen, Wenting ^{[1
]}

Wu, Zimo ^{[1
]}

Gao, Bingliang ^{[1
]}

Hu, Xianwei ^{[1
]}

Shi, Zhongning ^{[1
]}

Wang, Zhaowen ^{[1
]}

机构：

[1] Northeastern Univ, Sch Met, Shenyang 110819, Liaoning, Peoples R China

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2017年 / 247卷

基金：

中国国家自然科学基金;

关键词：

Ionic liquid analogues; AlCl3-amide; Electrical conductivity; Density; Viscosity; ELECTRODEPOSITION; ALKYLATION; ALUMINUM;

D O I：

10.1016/j.molliq.2017.09.091

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The density, viscosity and electrical conductivity of AlCl3-amide (amide = urea, acetamide, propionamide, butyramide) ionic liquid (IL) analogues with varied molar fractions of AICl(3) were measured at temperatures ranging from 313 K to 373 K. All the experimental values were fitted with the empirical equations. Meanwhile, the molar volume and molar conductivity of AlCl3-amide were also obtained. Based on the results, the difference in the properties of AlCl3-amide IL analogues are mainly attributed to the species of amide ligands, which have significant effects on complex structure, ionic interaction and hydrogen bonding of IL analogues. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：57 / 63

页数：7

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