A novel synthesis of aryl α-imino esters from aryl diazoacetate

被引：12

作者：

Huang, HX

Wan, YH

Chen, ZY

Hu, WH ^{[1
]}

机构：

[1] Chinese Acad Sci, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China

[2] Chinese Acad Sci, Union Lab Asymmetr Synth, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China

[3] Chinese Acad Sci, Grad Sch, Beijing, Peoples R China

来源：

SYNLETT | 2005年 / 16期

关键词：

alpha-imino ester; dirhodium(II) acetate; alpha-diazoacetate; ammonium ylide; aminal;

D O I：

10.1055/s-2005-872689

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aryl alpha-imino esters were synthesized from the reaction of aryl diazoacetate with arylamine in the presence of diethyl azodicarboxylate (DEAD) catalyzed by dirhodium acetate. The alpha-imino esters were formed through fragmentation of corresponding aminals.

引用

页码：2498 / 2500

页数：3

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