Halide enhancement of the luminescence of Cd10S4 thiolate clusters

被引：32

作者：

Adams, RD ^{[1
]}

Zhang, B ^{[1
]}

Murphy, CJ ^{[1
]}

Yeung, LK ^{[1
]}

机构：

[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 04期

关键词：

D O I：

10.1039/a809443h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New halide-substituted cluster anions [Cd10S4X4(SR)(12)](4-) (R = Ph, X = I, 2a; R = p-MeC6H4, X = I, 3a or Br, 3b) of the [Cd10S4(SR)(16)](4-) family have been prepared and characterized; investigations of their luminescence show that the introduction of the halide groups produces red shifts and significant enhancements in their emission intensities.

引用

页码：383 / 384

页数：2

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