Mesoscopic pattern formation of nanostructured polymer assemblies

被引:105
作者
Maruyama, N
Karthaus, O
Ijiro, K
Shimomura, M [1 ]
Koito, T
Nishimura, S
Sawadaishi, T
Nishi, N
Tokura, S
机构
[1] Hokkaido Univ, Res Inst Elect Sci, Sapporo, Hokkaido 060, Japan
[2] Hokkaido Univ, Grad Sch Sci, Sapporo, Hokkaido 060, Japan
[3] Hokkaido Univ, Grad Sch Environm Earth Sci, Sapporo, Hokkaido 060, Japan
来源
SUPRAMOLECULAR SCIENCE | 1998年 / 5卷 / 3-4期
关键词
polymer-surfactant polyion complexes; dissipative structure; hierarchical structuring; mesoscopic pattern;
D O I
10.1016/S0968-5677(98)00027-3
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hierarchical mesoscopic structures of the nanoscopic supramolecular assemblies, which consist of polyelectrolytes and bilayer-forming amphiphiles, are prepared by a simple and new solvent-casting method. Submicron scale 2-D structures, e.g. regular dots, stripes, and networks, are formed when highly diluted organic solutions of polymer assemblies are cast on solid surfaces. Dynamic mesoscopic regular structures, the so-called 'dissipative structures', formed in the non-equilibrium processes of solvent-casting are fixed as hierarchically structured polymer assemblies. (C) 1998 Elsevier Science Limited. All rights reserved.
引用
收藏
页码:331 / 336
页数:6
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