Regiodivergent Synthesis of Functionalized Indene Derivatives via Pt-Catalyzed Rautenstrauch Reaction of Propargyl Carbonates

被引：56
|
作者：
Zhao, Jinbo [1 ]
Clark, Daniel A. [1 ]
机构：
[1] Syracuse Univ, Dept Chem, Ctr Sci & Technol 1 014, Syracuse, NY 13244 USA
来源：
ORGANIC LETTERS | 2012年 / 14卷 / 07期
关键词：
ASYMMETRIC-SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; ALKYLATION REACTIONS; SUBSTITUTED INDENES; EFFICIENT FORMATION; INDANONES; CYCLIZATION; COMPLEXES; CYCLOISOMERIZATION; PLATINUM;
D O I：
10.1021/ol300158d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A regiodivergent synthesis of functionalized indene derivatives from a Pt-catalyzed Rautenstrauch reaction of propargyl carbonate is described. A one-pot Rautenstrauch/Tsuji-Trost reaction delivering 2-indanones was realized efficiently using this methodology.
引用
收藏
页码：1668 / 1671
页数：4
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