A first example of a reaction under viscous conditions: oxidation of solid benzoins with manganese dioxide

被引：15

作者：

Lou, Ji-Dong ^{[1
]}

Lu, Xiu L. ^{[1
]}

Marrogi, Aizen J. ^{[2
]}

Li, Feng ^{[3
]}

Gao, Chun-Ling ^{[4
]}

Yu, Xiaoping ^{[1
]}

机构：

[1] China Inst Metrol, Coll Life Sci, Hangzhou 310018, Zhejiang, Peoples R China

[2] Walter Reed Army Med Ctr, Dept Pathol & Area Lab Med, Washington, DC 20307 USA

[3] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

[4] Uniformed Serv Univ Hlth Sci, Ctr Prostate Dis Res, Bethesda, MD 20814 USA

来源：

MONATSHEFTE FUR CHEMIE | 2008年 / 139卷 / 06期

关键词：

viscous conditions; solid substrate; solvent-free reactions; oxidation; solid benzoins;

D O I：

10.1007/s00706-007-0800-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new, general, and efficient technique for the reaction of solid substrates under viscous conditions with shaking at room temperature is described, which can overcome some of the problems existing in common solvent-free reactions solids as the starting materials. In this manuscript we present as a first example of this method the oxidation of solid benzoins into the corresponding benzils using an environmentally friendly and inexpensive oxidant, manganese dioxide.

引用

页码：609 / 611

页数：3

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