Strictly correlated uniform electron droplets

被引:30
作者
Rasanen, E. [1 ]
Seidl, M. [2 ]
Gori-Giorgi, P. [3 ,4 ]
机构
[1] Univ Jyvaskyla, Dept Phys, Nanosci Ctr, FI-40014 Jyvaskyla, Finland
[2] Univ Regensburg, Inst Theoret Phys, D-93040 Regensburg, Germany
[3] Vrije Univ Amsterdam, Dept Theoret Chem, NL-1081 HV Amsterdam, Netherlands
[4] Vrije Univ Amsterdam, FEW, Amsterdam Ctr Multiscale Modeling, NL-1081 HV Amsterdam, Netherlands
来源
PHYSICAL REVIEW B | 2011年 / 83卷 / 19期
基金
芬兰科学院;
关键词
DENSITY-FUNCTIONAL THEORY; STRONG-INTERACTION LIMIT; EXCHANGE-CORRELATION-ENERGY;
D O I
10.1103/PhysRevB.83.195111
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We study the energetic properties of finite but internally homogeneous D-dimensional electron droplets in the strict-correlation limit. The indirect Coulomb interaction is found to increase as a function of the electron number, approaching the tighter forms of the Lieb-Oxford bound recently proposed by Rasanen et al. [Phys. Rev. Lett. 102, 206406 (2009)]. The bound is satisfied in three-, two-, and one-dimensional droplets, and in the latter case it is reached exactly-regardless of the type of interaction considered. Our results provide useful reference data for delocalized strongly correlated systems, and they can be used in the development and testing of exchange-correlation density functionals in the framework of density-functional theory.
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页数:8
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