Orientational uniaxial stretching of proton conducting perfluorinated membranes

被引：4
|
作者：
Primachenko, Oleg N. [1 ]
Kulvelis, Yuri, V [2 ]
Marinenko, Elena A. [1 ]
Gofman, Iosif, V [1 ]
Lebedev, Vasily T. [2 ]
Kononova, Svetlana, V [1 ]
Kuklin, Alexander, I [3 ,4 ]
Ivankov, Oleksandr I. [3 ]
Soloviov, Dmytro, V [3 ]
Chenneviere, Alexis [5 ]
机构：
[1] Russian Acad Sci, Inst Macromol Cpds, St Petersburg, Russia
[2] Petersburg Nucl Phys Inst, Orlova Roscha 1, Gatchina 188300, Leningrad Regio, Russia
[3] Joint Inst Nucl Res, Frank Lab Neutron Phys, Dubna, Russia
[4] Moscow Inst Phys & Technol, Dolgoprudnyi, Russia
[5] CEA Saclay, UMR12 CEA, Lab Leon Brillouin, CNRS, Gif Sur Yvette, France
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2022年 / 139卷 / 21期
关键词：
batteries and fuel cells; mechanical properties; membranes; structure-property relationships; SHORT-SIDE-CHAIN; TEMPERATURE-DEPENDENT PERFORMANCE; FUEL-CELL OPERATION; EXCHANGE MEMBRANES; INTERMEDIATE TEMPERATURE; THIN-FILMS; ELECTROLYTE; IONOMER; MORPHOLOGY; TRANSPORT;
D O I：
10.1002/app.52229
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The Aquivion (R)-type perfluorinated proton conducting membranes were studied subjected to a specially developed technique of uniaxial orientational stretching. Membranes were prepared from copolymer produced by aqueous-emulsion copolymerization and by pressing the melt copolymer precursor or by casting a solution of copolymer in sulfonyl alkaline form in dimethylformamide. The possibilities of the regulation of electrochemical and physical-chemical properties of Aquivion (R)-type membranes using the method of orientational stretching are demonstrated. Proton conductivity rises in the stretching direction due to the straightening of the pathways for protons in membranes found by small-angle neutron scattering technique.
引用
收藏
页数：15
相关论文
共 50 条
  • [1] Structure and property optimization of perfluorinated short side chain membranes for hydrogen fuel cells using orientational stretching
    Kulvelis, Yu. V.
    Ivanchev, S. S.
    Primachenko, O. N.
    Lebedev, V. T.
    Marinenko, E. A.
    Ivanova, I. N.
    Kuklin, A. I.
    Ivankov, O. I.
    Soloviov, D. V.
    RSC ADVANCES, 2016, 6 (110) : 108864 - 108875
  • [2] Microdetermination of silicon dioxide on the surface by sensors based on perfluorinated proton-conducting membranes
    Nikitin, S. E.
    Terukov, E. I.
    Timofeev, S. V.
    Manabaev, N. K.
    TECHNICAL PHYSICS, 2012, 57 (06) : 865 - 867
  • [3] Microdetermination of silicon dioxide on the surface by sensors based on perfluorinated proton-conducting membranes
    S. E. Nikitin
    E. I. Terukov
    S. V. Timofeev
    N. K. Manabaev
    Technical Physics, 2012, 57 : 865 - 867
  • [4] Effect of preparation conditions on nanostructural features of the NAFION® type perfluorinated proton conducting membranes
    Yu. V. Kul’velis
    V. T. Lebedev
    V. A. Trunov
    O. N. Primachenko
    S. Ya. Khaikin
    D. Torok
    S. S. Ivanchev
    Petroleum Chemistry, 2012, 52 : 565 - 570
  • [5] Effect of preparation conditions on nanostructural features of the NAFION® type perfluorinated proton conducting membranes
    Kul'velis, Yu. V.
    Lebedev, V. T.
    Trunov, V. A.
    Primachenko, O. N.
    Khaikin, S. Ya.
    Torok, D.
    Ivanchev, S. S.
    PETROLEUM CHEMISTRY, 2012, 52 (08) : 565 - 570
  • [6] Structure-Morphology-Property Relationships of Non-Perfluorinated Proton-Conducting Membranes
    Peckham, Timothy J.
    Holdcroft, Steven
    ADVANCED MATERIALS, 2010, 22 (42) : 4667 - 4690
  • [7] Montmorillonite functionalized with perfluorinated sulfonic acid for proton-conducting organic-inorganic composite membranes
    Kim, Youngkwon
    Lee, Jae Sung
    Rhee, Chang Houn
    Kim, Hae Kyung
    Chang, Hyuk
    JOURNAL OF POWER SOURCES, 2006, 162 (01) : 180 - 185
  • [8] Microdetermination of titanium on the developed silicon surface using cells made of perfluorinated proton-conducting membranes
    Nikitin, S. E.
    Terukov, E. I.
    Kon'kov, O. I.
    Bobyl', A. V.
    Timofeev, S. V.
    TECHNICAL PHYSICS, 2013, 58 (05) : 766 - 769
  • [9] State of the art and prospects in the development of proton-conducting perfluorinated membranes with short side chains: A review
    Primachenko, Oleg N.
    Marinenko, Elena A.
    Odinokov, Alexey S.
    Kononova, Svetlana V.
    Kulvelis, Yuri V.
    Lebedev, Vasily T.
    POLYMERS FOR ADVANCED TECHNOLOGIES, 2021, 32 (04) : 1386 - 1408
  • [10] Microdetermination of titanium on the developed silicon surface using cells made of perfluorinated proton-conducting membranes
    S. E. Nikitin
    E. I. Terukov
    O. I. Kon’kov
    A. V. Bobyl’
    S. V. Timofeev
    Technical Physics, 2013, 58 : 766 - 769
12345