Porous carbon-coated ZnO nanoparticles derived from low carbon content formic acid-based Zn(II) metal-organic frameworks towards long cycle lithium-ion anode material

Single-C formic acid-based metal-organic frameworks (MOFs) are used to construct novel ZnO@porous carbon matrix nanocomposites by controlled pyrolysis. In the constructed nanocomposites, the porous carbon matrices act as a confined support to prevent agglomeration of the ZnO nanoparticles and create a rapid electron conductive network. Meanwhile, the well-defined, continuous porous structured MOFs provide a large specific surface area, which increases the contact of electrolyte-electrode and improves the penetration of electrolyte. Especially, the reasonable choice of formic acid-based MOFs construct the low carbon content composite, which contribute to the high energy density and long cycle life. The constructed nanocomposites show stable, ultrahigh rate lithium ion storage properties of 650 mAh g(-1) at charge/discharge rate of 1 C even after 200 cycles. (C) 2016 Elsevier Ltd. All rights reserved.