Poly(2,7-dibenzosilole): A blue light emitting polymer

被引：261
|
作者：
Chan, KL
McKiernan, MJ
Towns, CR
Holmes, AB
机构：
[1] Univ Cambridge, Dept Chem, Melville Lab Polymer Synth, Cambridge CB2 1EW, England
[2] Univ Melbourne, Bio21 Inst, Parkville, Vic 3010, Australia
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 21期
关键词：
D O I：
10.1021/ja0508065
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
2,7-Disubstituted dibenzosilole monomers have been prepared by the selective trans-lithiation of 4,4′-dibromo-2,2′-diiodobiphenyl followed by silylation with dichlorodihexylsilane. Suzuki copolymerization of dibromo and bis(boronate) monomers afforded poly(9,9-dihexyl-2,7-dibenzosilole) which showed better efficiency than the corresponding polyfluorene in a single layer light emitting device. Preliminary studies demonstrated this to be a promising blue light emitting polymer. Copyright © 2005 American Chemical Society.
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收藏
页码：7662 / 7663
页数：2
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