Controllable dielectric performance of polymer composites via the Coulomb-blockade effect with core-shell structured nano-particles

被引：39

作者：

Yang, Dan ^{[1
,2
]}

Huang, Shuo ^{[2
,3
]}

Ruan, Mengnan ^{[2
,3
]}

Wu, Yibo ^{[1
,2
]}

Li, Shuxin ^{[1
,2
]}

Wang, Hao ^{[1
,2
]}

Zhang, Jinyu ^{[1
]}

Ma, Haonan ^{[1
]}

Guo, Wenli ^{[1
,2
]}

Zhang, Liqun ^{[3
]}

机构：

[1] Beijing Inst Petrochem Technol, Dept Mat Sci & Engn, Beijing 102617, Peoples R China

[2] Beijing Key Lab Special Elastomer Composite Mat, Beijing 102617, Peoples R China

[3] Beijing Univ Chem Technol, Dept Mat Sci & Engn, Beijing 100029, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY C | 2017年 / 5卷 / 31期

基金：

中国国家自然科学基金; 北京市自然科学基金;

关键词：

HIGH-ENERGY DENSITY; HIGH PERMITTIVITY; BARIUM-TITANATE; POLY(DOPAMINE) FUNCTIONALIZATION; BREAKDOWN STRENGTH; TIO2; NANOPARTICLES; BIOMIMETIC METHOD; NANOCOMPOSITES; RUBBER; FILMS;

D O I：

10.1039/c7tc00978j

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Designed core-shell structured titanium dioxide-poly(dopamine)-silver (TiO2-PDA-Ag) particles were prepared via self-polymerization of poly(dopamine) and electroless plating of nano-silver particles. The poly(dopamine) layer was used not only to improve the interfacial interaction between TiO2 and the nitrile-butadiene rubber (NBR) matrix but also as chemisorption sites for silver ions. Then the TiO2-PDA-Ag particles were introduced into the NBR matrix to prepare dielectric composites. The effect of the nano-Ag content on morphology, dielectric properties, and electrical properties of the composites was thoroughly investigated. It was found that the Coulomb-blockade effect of nano-Ag particles led to the composites with relatively low dielectric loss and relatively high electrical breakdown strength. This simple and effective approach provides a promising route to adjust the dielectric properties of dielectric composites via the Coulomb-blockade effect.

引用

页码：7759 / 7767

页数：9

共 40 条

[1] Quantum effects in Coulomb blockade [J].

Aleiner, IL ;

Brouwer, PW ;

Glazman, LI .

PHYSICS REPORTS-REVIEW SECTION OF PHYSICS LETTERS, 2002, 358 (5-6) :309-440

[2] Dopamine-Melanin Film Deposition Depends on the Used Oxidant and Buffer Solution [J].

Bernsmann, Falk ;

Ball, Vincent ;

Addiego, Frederic ;

Ponche, Arnaud ;

Michel, Marc ;

de Almeida Gracio, Jose Joaquin ;

Toniazzo, Valerie ;

Ruch, David .

LANGMUIR, 2011, 27 (06) :2819-2825

[3]

Boumhara K, 2015, J IND ENG CHEM, V29, P146

[4] Nano-KTN@ Ag/PVDF composite films with high permittivity and low dielectric loss by introduction of designed KTN/Ag core/shell nanoparticles [J].

Chen, Gaoru ;

Wang, Xuan ;

Lin, Jiaqi ;

Yang, Wenlong ;

Li, Haidong ;

Wen, Yinian ;

Li, Landi ;

Jiang, Zhichao ;

Lei, Qingquan .

JOURNAL OF MATERIALS CHEMISTRY C, 2016, 4 (34) :8070-8076

[5] Fabrication and dielectric characterization of advanced BaTiO3/polyimide nanocomposite films with high thermal stability [J].

Dang, Zhi-Min ;

Lin, You-Qin ;

Xu, Hai-Ping ;

Shi, Chang-Yong ;

Li, Sheng-Tao ;

Bai, Jinbo .

ADVANCED FUNCTIONAL MATERIALS, 2008, 18 (10) :1509-1517

[6] Flexible Nanodielectric Materials with High Permittivity for Power Energy Storage [J].

Dang, Zhi-Min ;

Yuan, Jin-Kai ;

Yao, Sheng-Hong ;

Liao, Rui-Jin .

ADVANCED MATERIALS, 2013, 25 (44) :6334-6365

[7] Preparation and dielectric properties of surface modified TiO2/silicone rubber nanocomposites [J].

Dang, Zhi-Min ;

Xia, Yu-Juan ;

Zha, Jun-Wei ;

Yuan, Jin-Kai ;

Bai, Jinbo .

MATERIALS LETTERS, 2011, 65 (23-24) :3430-3432

[8] Mechanism of high dielectric performance of polymer composites induced by BaTiO3-supporting Ag hybrid fillers [J].

Fang, Fang ;

Yang, Wenhu ;

Yu, Shuhui ;

Luo, Suibin ;

Sun, Rong .

APPLIED PHYSICS LETTERS, 2014, 104 (13)

[9] Highly Conductive One-Dimensional Nanofibers: Silvered Electrospun Silica Nanofibers via Poly(dopamine) Functionalization [J].

Fu, Ye ;

Liu, Li ;

Zhang, Liqun ;

Wang, Wencai .

ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (07) :5105-5112

[10] A Hybrid Material Approach Toward Solution-Processable Dielectrics Exhibiting Enhanced Breakdown Strength and High Energy Density [J].

Han, Kuo ;

Li, Qi ;

Chanthad, Chalathorn ;

Gadinski, Matthew R. ;

Zhang, Guangzu ;

Wang, Qing .

ADVANCED FUNCTIONAL MATERIALS, 2015, 25 (23) :3505-3513

← 1 2 3 4 →