Monomeric and Dimeric Disulfide Complexes of Nickel(II)

被引：20
作者：
Iluc, Vlad M. [1 ]
Laskowski, Carl A. [1 ]
Brozek, Carl K. [1 ]
Harrold, Nicole D. [1 ]
Hillhouse, Gregory L. [1 ]
机构：
[1] Univ Chicago, Dept Chem, Gordon Ctr Integrat Sci, Chicago, IL 60637 USA
来源：
INORGANIC CHEMISTRY | 2010年 / 49卷 / 15期
基金：
美国国家科学基金会;
关键词：
MOLECULAR-STRUCTURES; CRYSTAL-STRUCTURE; COA SYNTHASE; HYDRODESULFURIZATION; REACTIVITY; INSIGHTS; BOND;
D O I：
10.1021/ic101242c
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Elemental sulfur reacts with a bulky bis(phosphine)nickel(0) complex to give a monomeric nickel(II),eta(2)-disulfido complex, oxidation of which results in the elimination of sulfur with dimerization to give an eta(2),eta(2)-disulfidodinickel(II) derivative in which the S S bond can be reductively cleaved in a redox-reversible fashion.
引用
收藏
页码：6817 / 6819
页数：3
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