ME and M=E complexes of iron and cobalt that emphasize three-fold symmetry (EO, N, NR)

被引：166

作者：

Saouma, Caroline T. ^{[1
]}

Peters, Jonas C. ^{[1
]}

机构：

[1] CALTECH, Div Chem & Chem Engn, Pasadena, CA 91125 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2011年 / 255卷 / 7-8期

基金：

美国国家科学基金会;

关键词：

Atom and group transfer; Metal-to-ligand multiple bond; Oxos; Imides; Nitrides; C-H ACTIVATION; SPIN OXOIRON(IV) COMPLEX; NITROGEN ATOM-TRANSFER; RAY CRYSTAL-STRUCTURE; METAL-OXO COMPLEXES; ELECTRONIC-STRUCTURE; IMIDO COMPLEXES; SPECTROSCOPIC CHARACTERIZATION; MOLECULAR-STRUCTURE; NITRENE TRANSFER;

D O I：

10.1016/j.ccr.2011.01.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mid-to-late transition metal complexes that feature terminal, multiply bonded ligands such as oxos, imides, and nitrides have been invoked as intermediates in several catalytic transformations of synthetic and biological significance. Until about ten years ago, isolable examples of such species were virtually unknown. Over the past decade or so, numerous chemically well-defined examples of such species have been discovered. In this context, the present review summarizes the development of 4- and 5-coordinate Fe(E) and Co(E) species under local three-fold symmetry. (C) 2011 Elsevier By. All rights reserved.

引用

页码：920 / 937

页数：18

共 153 条

[31] TRANSITION-METAL IMIDO COMPLEXES [J].

CUNDARI, TR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (20) :7879-7888

[32] [Me2NN]Co(η6-toluene):: O=O, N= N, and O=N bond cleavage provides, β-diketiminato cobalt μ-oxo and imido complexes [J].

Dai, XL ;

Kapoor, P ;

Warren, TH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (15) :4798-4799

[33] Considering FeII/IV redox processes as mechanistically relevant to the catalytic hydrogenation of olefins by [PhBpiPr3]Fe-Hx species [J].

Daida, EJ ;

Peters, JC .

INORGANIC CHEMISTRY, 2004, 43 (23) :7474-7485

[34] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF TRANS-BIS(2,6-DIISOPROPYLPHENYLIMIDO)BIS-(TRIMETHYLPHOSPHINO)RUTHENIUM(IV) - THE 1ST STRUCTURAL DETERMINATION OF A TERMINAL IMIDO RUTHENIUM COMPOUND [J].

DANOPOULOS, AA ;

WILKINSON, G ;

HUSSAINBATES, B ;

HURSTHOUSE, MB .

POLYHEDRON, 1992, 11 (22) :2961-2964

[35] Catalytic asymmetric C-H activation of alkanes and tetrahydrofuran [J].

Davies, HML ;

Hansen, T ;

Churchill, MR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (13) :3063-3070

[36] Catalytic C-H functionalization by metal carbenoid and nitrenoid insertion [J].

Davies, Huw M. L. ;

Manning, James R. .

NATURE, 2008, 451 (7177) :417-424

[37] Spectroscopic and quantum chemical studies on low-spin FeIV=O complexes:: Fe-O bonding and its contributions to reactivity [J].

Decker, Andrea ;

Rohde, Jan-Uwe ;

Klinker, Eric J. ;

Wong, Shaun D. ;

Que, Lawrence, Jr. ;

Solomon, Edward I. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (51) :15983-15996

[38] X-ray absorption spectroscopy and density functional theory studies of [(H3buea)FeIII-X]n- (X = S2-, O2-, OH-):: Comparison of bonding and hydrogen bonding in oxo and sulfido complexes [J].

Dey, Abhishek ;

Hocking, Rosalie K. ;

Larsen, Peter ;

Borovik, Andrew S. ;

Hodgson, Keith O. ;

Hedman, Britt ;

Solomon, Edward I. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (30) :9825-9833

[39] CATALYTIC METHODS FOR METAL CARBENE TRANSFORMATIONS [J].

DOYLE, MP .

CHEMICAL REVIEWS, 1986, 86 (05) :919-939

[40] Nitridomanganese(V) complexes: Design, preparation, and use as nitrogen atom-transfer reagents [J].

DuBois, J ;

Tomooka, CS ;

Hong, J ;

Carreira, EM .

ACCOUNTS OF CHEMICAL RESEARCH, 1997, 30 (09) :364-372

← 1 2 3 4 5 6 7 8 9 10 →