ME and M=E complexes of iron and cobalt that emphasize three-fold symmetry (EO, N, NR)

被引：166

作者：

Saouma, Caroline T. ^{[1
]}

Peters, Jonas C. ^{[1
]}

机构：

[1] CALTECH, Div Chem & Chem Engn, Pasadena, CA 91125 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2011年 / 255卷 / 7-8期

基金：

美国国家科学基金会;

关键词：

Atom and group transfer; Metal-to-ligand multiple bond; Oxos; Imides; Nitrides; C-H ACTIVATION; SPIN OXOIRON(IV) COMPLEX; NITROGEN ATOM-TRANSFER; RAY CRYSTAL-STRUCTURE; METAL-OXO COMPLEXES; ELECTRONIC-STRUCTURE; IMIDO COMPLEXES; SPECTROSCOPIC CHARACTERIZATION; MOLECULAR-STRUCTURE; NITRENE TRANSFER;

D O I：

10.1016/j.ccr.2011.01.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mid-to-late transition metal complexes that feature terminal, multiply bonded ligands such as oxos, imides, and nitrides have been invoked as intermediates in several catalytic transformations of synthetic and biological significance. Until about ten years ago, isolable examples of such species were virtually unknown. Over the past decade or so, numerous chemically well-defined examples of such species have been discovered. In this context, the present review summarizes the development of 4- and 5-coordinate Fe(E) and Co(E) species under local three-fold symmetry. (C) 2011 Elsevier By. All rights reserved.

引用

页码：920 / 937

页数：18

共 153 条

[1]

Albright T.A., 1985, ORBITAL INTERACTIONS

[2] The geometric and electronic structure of [(cyclam-acetato)Fe(N)+]:: A genuine iron(V) species with a ground-state spin S=1/2 [J].

Aliaga-Alcalde, N ;

George, SD ;

Mienert, B ;

Bill, E ;

Wieghardt, K ;

Neese, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (19) :2908-2912

[3] RETRACTED: A late-transition metal oxo complex: K7Na9[O=PtIV(H2O)L2]. L = [PW9O34]9- (Retracted Article) [J].

Anderson, TM ;

Neiwert, WA ;

Kirk, ML ;

Piccoli, PMB ;

Schultz, AJ ;

Koetzle, TF ;

Musaev, DG ;

Morokuma, K ;

Cao, R ;

Hill, CL .

SCIENCE, 2004, 306 (5704) :2074-2077

[4] The Electronic Structure of the Vanadyl Ion [J].

Ballhausen, C. J. ;

Gray, Harry B. .

INORGANIC CHEMISTRY, 1962, 1 (01) :111-122

[5] UNUSUAL ELECTRONIC-SPECTRA OF THE PSEUDOTETRAHEDRAL COMPLEX [TRIS((3,5-DIMETHYL-1-PYRAZOLYL)ETHYL)AMINE]COBALT(II) BIS(TETRAPHENYLBORATE) [J].

BANCI, L ;

BENELLI, C ;

GATTESCHI, D ;

MANI, F .

INORGANIC CHEMISTRY, 1982, 21 (03) :1133-1136

[6] Synthesis and hydrogenation of bis(imino)pyridine iron Imides [J].

Bart, SC ;

Lobkovsky, E ;

Bill, E ;

Chirik, PJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (16) :5302-5303

[7]

BELL B, 1972, INORG CHIM ACTA, V6, P635

[8] Initial members of the family of molecular mid-valent high-nuclearity iron nitrides:: [Fe4N2X10]4- and [Fe10N8X12]5- (X = Cl-, Br-) [J].

Bennett, MV ;

Stoian, S ;

Bominaar, EL ;

Münck, E ;

Holm, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (35) :12378-12386

[9] Electronic structure and spectroscopy of "superoxidized" iron centers in model systems: theoretical and experimental trends [J].

Berry, John F. ;

George, Serena DeBeer ;

Neese, Frank .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (30) :4361-4374

[10] An octahedral coordination complex of iron(VI) [J].

Berry, John F. ;

Bill, Eckhard ;

Bothe, Eberhard ;

George, Serena DeBeer ;

Mienert, Bernd ;

Neese, Frank ;

Wieghardt, Karl .

SCIENCE, 2006, 312 (5782) :1937-1941

← 1 2 3 4 5 6 7 8 9 10 →