One-pot synthesis of end-functionalised soluble star-shaped polymers by living ring-opening metathesis polymerisation using a molybdenum-alkylidene catalyst

被引：10

作者：

Sun, Zelin ^{[1
]}

Nomura, Kotohiro ^{[1
]}

机构：

[1] Tokyo Metropolitan Univ, Dept Chem, Fac Sci, 1-1 Minami Osawa, Hachioji, Tokyo 1920397, Japan

来源：

RSC ADVANCES | 2018年 / 8卷 / 49期

基金：

日本学术振兴会;

关键词：

TRANSFER RADICAL POLYMERIZATION; POLY(ETHYLENE GLYCOL); ROMP; ADMET; ARCHITECTURES; COPOLYMERS; COMPLEXES; CHEMISTRY;

D O I：

10.1039/c8ra05229h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Precise synthesis of soluble star-shaped polymers has been achieved by adopting living ring-opening metathesis polymerisation (ROMP) using a molybdenum-alkylidene catalyst with sequential addition of norbornene and cross-linking agent; the method provides efficient one-pot synthesis of high molecular weight end-functionalised star-shaped polymers (M-n = >1.37 x 10(5)) with more arms (branching) with rather low PDI values (M-w/M-n = 1.17-1.37) under the optimised conditions.

引用

页码：27703 / 27708

页数：6

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