Mixed unsymmetric oxadiazoline and/or imine platinum(II) complexes

被引：29
作者：
Lasri, Jamal
Charmier, M. Adilia Januario
da Silva, M. Fatima C. Guedes
Pombeiro, Armando J. L.
机构：
[1] Univ Tecn Lisboa, Ctr Quim Estrutural, Inst Super Tecn, Complexo 1, P-1049001 Lisbon, Portugal
[2] Univ Lusofona Human Tecnol, P-1749024 Lisbon, Portugal
来源：
DALTON TRANSACTIONS | 2007年 / 30期
关键词：
D O I：
10.1039/b704329e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Iminoacylation of acetone oxime Me2C=NOH 2 upon reaction with trans-[PtCl2(NCCH2CO2Me)(2)] 1 and [2 + 3] cycloaddition of acyclic nitrone -O+N(Me)=C(H)(C6H4Me-4) 3 to a nitrile figand in 1 lead to the formation of mono-imine trans-[PtCl2(imine-a)(NCCH2CO2Me)] 4 [imine-a = NH=C(CH2CO2Me)ON=CMe2] and rnono-oxadiazoline trans-[PtCl2(oxadiazoline-a)(NCCHCO2Me)] 6 [oxadiazoline-a = N=C(CH2CO2Me)ON(Me)C(H)(C6H4Me-4)] unsymmetric mixed ligand complexes, respectively, as the main products. Reactions of 6 or 4 with acetone oxime 2, cyclic nitrone -O+N=CHCH2CH2CMe2 8 or N,N-diethylhydroxylamine 11 give access, in moderate to good yields, to the unsvmrnetric mixed ligand oxadiazoline and/or imine complexes trans-[PtCl2(oxadiazoline-a)(imine-a)] 9, trans-[PtCl2(oxadiazoline-a)(oxadiazoline-b)] 10 [oxadiazoline-b =N=C(CH2CO2Me)ONC(H)CH2CH2CMe2], trans-[PtCl2(imine-a)(imine-b)] 12 [imine-b NH=C(CH2CO2Me)ONEt2] or trans-[PtCl2(imine-a)(oxadiazoline-b)] 13. The cis mono-imine mixed ligand complex cis-[PtCl2(imine-a)(NCCH2CO2Me)(2)] 4a is the major product from the reaction of cis-[PtCl2(NCCH2CO2Me)(2)] 1a with the oxime 2, while the di-imine compound cis-[PtCl2(imine-a)(2)] 5a is a minor product. Reaction of cis-[PtCl2(imine-a)(NCCH2CO2Me)] 4a with -N,N-diethythydroxylamine 11 or the cyclic nitrone 8 affords, in good yields, the unsyrnmetric mixed ligand complexes cis-[PtCl2(imine-a)(imine-b)] 12a or ciy-[PtCl2(imine-a)(oxadiazoline-b)] 13a, respectively All these complexes were characterized by elemental analyses, IR and H-1, C-13 and Pt-195 NMR spectroscopies, and FAB(+)-MS. The X-ray structural analysis of trans-[PtCl2 {NH=C(CH2CO2Me)ON=CMe2}(NCCH2CO2Me)] 4 is also reported.
引用
收藏
页码：3259 / 3266
页数：8
相关论文
共 50 条
[31]   SYNTHESIS AND NMR SPECTRAL STUDIES OF MIXED PHOSPHINE PLATINUM(II) COMPLEXES [J].
GOEL, AB ;
GOEL, S ;
CLARK, HC .
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1981, 11 (04) :289-298
[32]   MIXED DIMETHYLSULFOXIDE-THIOCARBONYL DONOR COMPLEXES OF PLATINUM(II) HALIDES [J].
FARAGLIA, G ;
BARBARO, F ;
SITRAN, S .
JOURNAL OF COORDINATION CHEMISTRY, 1990, 21 (01) :63-70
[33]   Synthesis, spectroscopy and electrochemistry of mixed-ligand complexes of platinum(II) and palladium(II) [J].
Anbalagan, V ;
Srinivasan, R ;
Pallavi, KS .
TRANSITION METAL CHEMISTRY, 2001, 26 (06) :603-607
[34]   Synthesis and characterization of novel trans-mixed diamine platinum(II) and platinum(IV) complexes [J].
Shamsuddin, S ;
Ali, MS ;
Huang, S ;
Khokhar, AR .
JOURNAL OF COORDINATION CHEMISTRY, 2002, 55 (06) :659-665
[35]   Synthesis and characterization of mixed valence μ-alkoxo-diiron(II,III) complexes with an unsymmetric dinucleating ligand [J].
Suzuki, M ;
Fujinami, S ;
Hibino, T ;
Hori, H ;
Maeda, Y ;
Uehara, A ;
Suzuki, M .
INORGANICA CHIMICA ACTA, 1998, 283 (01) :124-135
[36]   CHEMISTRY OF MIXED-LIGAND COMPLEXES OF PLATINUM - A STUDY OF THE CARBON-MONOXIDE REACTION WITH TRICHLOROSTANNYL PLATINUM(II) COMPLEXES [J].
GOEL, AB ;
GOEL, S .
INORGANICA CHIMICA ACTA-LETTERS, 1983, 77 (02) :L53-L55
[37]   SOME MIXED-LIGAND PALLADIUM(II) COMPLEXES AND COMPARISON OF THEIR PHOTOSENSITIZING ABILITY WITH ANALOGOUS PLATINUM(II) COMPLEXES [J].
PUTHRAYA, KH ;
SRIVASTAVA, TS .
POLYHEDRON, 1985, 4 (09) :1579-1584
[38]   Synthesis, characterization, structure and catalytic activity of (NNN) tridentate azo-imine nickel(II), palladium(II) and platinum(II) complexes [J].
Mandal, Paritosh ;
Lin, Chia-Her ;
Brandao, Paula ;
Mal, Dasarath ;
Felix, Vitor ;
Pratihar, Jahar Lal .
POLYHEDRON, 2016, 106 :171-177
[39]   Platinum(II) and mixed platinum(II)/gold(I) σ-alkynyl complexes.: The first anionic σ-alkynyl metal polymers [J].
Vicente, J ;
Chicote, MT ;
Alvarez-Falcón, MM ;
Jones, PG .
ORGANOMETALLICS, 2005, 24 (11) :2764-2772
[40]   Luminescent, Redox-Active Dithiolatobis(imine)platinum(II) Divergent Complexes with Exchangeable Imine Ligands: An Experimental/Computational Study Versus Their Diiminedithiolatoplatinum(II) Convergent Congeners [J].
Smith, Jacob B. ;
Otten, Brooke M. ;
Derry, Paul J. ;
Browning, Charles ;
Bodenstedt, Kurt W. ;
Sandridge, Jessie H. ;
Satumtira, Nisa T. ;
Zilaie, Mina ;
Payne, Jon ;
Nuti, Rathna ;
Omary, Mohammad A. ;
Smucker, Bradley W. .
COMMENTS ON INORGANIC CHEMISTRY, 2019, 39 (04) :188-215
12345