Gold corroles

被引：78

作者：

Alemayehu, Abraham B.

Ghosh, Abhik ^{[1
]}

机构：

[1] Univ Tromso, Dept Chem, N-9037 Tromso, Norway

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2011年 / 15卷 / 02期

关键词：

gold; corrole; octabromocorrole; REDUCTIVE DEMETALATION;

D O I：

10.1142/S1088424611003045

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Although a variety of conditions proved unsuccessful for gold insertion into beta-unsubstituted meso-triarylcorroles, refluxing free-base beta-octabromo-meso-triarylcorrole ligands, H-3[Br8T(p-X-P)C] (X = MeO, n-Bu, CH3, H, and CF3), with chloroauric acid in dichloromethane containing a small amount of triethylamine for 30 min led to 54-65% yields of the corresponding gold complexes.

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收藏

页码：106 / 110

页数：5

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