Synthesis, crystal structure and fluorescence of a new triazolated-bridged 2-D coordination polymer

被引：8

作者：

Liu, Bing ^{[1
]}

Zhou, Zhi-Qiang

Zhang, Xiu-Cheng

Zhang, Xian-You

机构：

[1] NE Forest Univ, Coll Sci, Harbin 150040, Peoples R China

[2] Harbin Univ Sci & Technol, Mat Sci & Engn Coll, Harbin 150040, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2007年 / 10卷 / 09期

关键词：

Zn(II); crystal structure; 1,2,4-triazole; fluorescence; topology;

D O I：

10.1016/j.inoche.2007.06.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the 2-D coordination polymer [Zn(L)Cl](n) (HL = 3-amino-1H-1,2,4-triazole) synthesized by diffusion method, L- ligands link Zn2+ to form 6- and 16-membered rings. The interconnection of the two kinds of rings results in a 2-D network, which features a (4, 82) topological network. Hydrogen bonds connect the neighboring plane-symmetry layers into a 3-D framework. The fluorescence with emission at 416 nm is assigned to LMCT. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：1095 / 1098

页数：4

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