A Highly Stable 3D Luminescent Indium-Polycarboxylic Framework for the Turn-off Detection of UO22+, Ru3+, and Biomolecule Thiamines

被引：53

作者：

Du, Ning ^{[1
]}

Song, Jian ^{[1
]}

Li, Shuang ^{[1
]}

Chi, Yu-Xian ^{[1
]}

Bai, Feng-Ying ^{[1
]}

Xing, Yong-Heng ^{[1
]}

机构：

[1] Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China

来源：

ACS APPLIED MATERIALS & INTERFACES | 2016年 / 8卷 / 42期

基金：

中国国家自然科学基金;

关键词：

indium complexes; 1,3,5-triazine-2,4,6-triamine hexaacetic acid (H(6)TTHA); metal ions; thiamines; luminescent sensing; METAL-ORGANIC FRAMEWORKS; HYDROGEN STORAGE; COORDINATION POLYMERS; MAGNETIC-PROPERTIES; POROUS MATERIALS; ADSORPTION; COMPLEXES; LIGAND; NITROBENZENE; EMISSION;

D O I：

10.1021/acsami.6b09456

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Hydrothermal reaction of the multidentate organic ligand (H(6)TTHA) with indium chloride (InCl3) produced highly stable 3D luminescent indium-organic framework [In-2(OH)(2)(H(2)TTHA)(H2O)(2)](n) (1). Complex 1 exhibits remarkable luminescent properties, especially the multifunction sensitivity and selectivity for detecting Ru3+, UO22+; as well as small biomolecules thiamines (TPP, TMP, and TCl) based on a "turn-off" manner. In particular, the pyrophosphate groups of TPP and the phosphate groups of TMP could further affect the quenching rate, leading to different luminescent responds. In addition, we also discussed and proved the luminescence quenching mechanism in detail through comparative test and PXRD characterization. Therefore, complex 1 could be used as a kind of excellent luminescence sensor to detect Ru3+, UO22+, and thiamines (TPP, TMP, and TCl).

引用

页码：28718 / 28726

页数：9

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