(1R,2R)-N,N′-Dimethylcyclohexane-1,2-diamine

被引:3
作者
Strohmann, Carsten [1 ]
Gessner, Viktoria H. [1 ]
Damme, Alexander [1 ]
Koller, Stephan [1 ]
Daeschlein, Christian [1 ]
机构
[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词
D O I
10.1107/S1600536808006119
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The molecule of the title compound, C8H18N2, possesses C-2 symmetry. Owing to its stereochemistry, it is used in the synthesis of chiral ligands and metal complexes for asymmetric synthesis. The cyclohexane ring shows a chair conformation with the amino groups in equatorial positions. Contrary to the literature, the title compound is not a liquid, but a crystalline solid at room temperature ( 293 K). The absolute configuration is assigned from the synthesis.
引用
收藏
页码:O687 / U1136
页数:10
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