Synthesis and characterization of polymers derived from selenophene

被引：0

作者：

del Valle, MA

Moreno, J

Díaz, FR

Tagle, LH

Bernède, JC

Tregoüet, Y

机构：

[1] Pontificia Univ Catolica Chile, Fac Quim, Dept Quim Organ, Lab Polimeros, Santiago, Chile

[2] FSTN, GPSE, Equipe Couches Minces & Mat Nouveaux, F-44322 Nantes 3, France

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2001年 / 81卷 / 08期

关键词：

2,5-selenophen-oxo-1,4-phenylen-selenide-1,4-phenylene-oxo; 2,5-selenophen-oxo-1,4-phenylen-diselenide-1,4-phenylen-diselenide-1,4-phenylen-oxo; poly(2,5-selenophen-oxo-1,4-phenylen-diselenide-1,4-phenylene-oxo); selenophene derivatives;

D O I：

暂无

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of poly(2,5-selenophen-oxo-1,4-phenylen-selenide-1,4-phenylene-oxo) (I) and poly(2,5-selenophen-oxo-1,4-phenylen-diselenide-1,4-phenylen-oxo) (II) by reaction of 2,5-bis(1,4-bromo-phenylen-oxo-) -selenophene with sodium selenide or diselenide, respectively, using dimethylformamide as solvent, is described. Both monomers and polymers were characterized by elemental analysis, melting point, and FTIR spectroscopy. Polymers I and II were doped with iodine and SbF5 and characterized by SEM and XPS. Also, the conductivity and the T-g values were determined. For both polymers the best doping agent was iodine, although polymer II always presented higher conductivity, reaching values of about 6.10(-9) S.cm(-1). The T-g values suggest a likely crosslinking of the chains in polymer II when doped with SbF5. (C) 2001 John Wiley & Sons, Inc.

引用

页码：2019 / 2026

页数：8