A highly substituted pyrazinophane generated from a quinoidal system via a cascade reaction

被引：9

作者：

Anderson, Christopher L. ^{[1
,2
]}

Liang, Jiatao ^{[1
,2
]}

Teat, Simon J. ^{[3
]}

Garzon-Ruiz, Andres ^{[4
]}

Nenon, David P. ^{[2
,5
]}

Navarro, Amparo ^{[6
]}

Liu, Yi ^{[1
]}

机构：

[1] Lawrence Berkeley Natl Lab, Mol Foundry, One Cyclotron Rd, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[3] Lawrence Berkeley Natl Lab, Adv Light Source, One Cyclotron Rd, Berkeley, CA 94720 USA

[4] Univ Castilla La Mancha, Fac Pharm, Dept Phys Chem, Albacete 02071, Spain

[5] Lawrence Berkeley Natl Lab, Mat Sci Div, One Cyclotron Rd, Berkeley, CA 94720 USA

[6] Univ Jaen, Fac Expt Sci, Dept Phys & Analyt Chem, Jaen 23071, Spain

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 32期

关键词：

VAPOR-DEPOSITION; MACRO RINGS; CHEMISTRY; SPACE; BOND;

D O I：

10.1039/d0cc00916d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The generation of a highly-substituted [2.2](2,5)pyrazinophane via a cascade reaction is presented. The pyrazinophane product is formed via the dimerization of a member of the para-azaquinodimethane (p-AQM) family of conjugated quinoidal compounds-reactivity that sheds light on the nature of stability in p-AQMs. Additionally, the electronic and structural nature of this highly-strained ring system are characterized.

引用

页码：4472 / 4475

页数：4

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