Synthesis and characterization of novel copolymer containing pyridylazo-2-naphthoxyl group via reversible addition-fragmentation chain transfer (RAFT) polymerization

被引：12

作者：

Zhou, Di ^{[1
,2
]}

Zhu, Xiulin ^{[1
]}

Zhu, Jian ^{[1
]}

Cheng, Zhenping ^{[1
]}

机构：

[1] Suzhou Univ, Sch Chem & Chem Engn Soochow, Key Lab Organ Synth Jiangsu Prov, Suzhou 215006, Peoples R China

[2] Changshu Inst Technol, Dept Chem, Jiangsu Key Lab Adv Funct Mat, Changshu 215500, Peoples R China

来源：

POLYMER | 2008年 / 49卷 / 13-14期

基金：

中国国家自然科学基金;

关键词：

reversible addition-fragmentation chain transfer (RAFT); copolymerization; 1-(2-Pyridylazo)-2-naphthol (PAN);

D O I：

10.1016/j.polymer.2008.05.011

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A novel monomer containing pyridylazo-2-naphthoxyl group, 1-(1-(4-vinylbenzyloxy)naphthalen-2-yl)-2-(pyridin-2-yl)diazene (VBNPA), was successfully synthesized and copolymerized with styrene (St) in N,N-dimethyl formamide (DMF) via reversible addition-fragmentation chain transfer (RAFT) polymerization using 2-cyanoprop-2-yl-1-dithionaphthalate (CPDN) as RAFT agent. The polymerization behavior exhibited "living"/controlled characters. The obtained copolymer, poly(St-co-VBNPA), with pre-determinable molecular weight and narrow molecular weight distribution can be used as a carrier in metal ion detection and analysis via pre-concentration technique. The copolymer-metal ion (copper (Cu) and europium (Eu)) complexes were prepared and characterized. (c) 2008 Elsevier Ltd. All rights reserved.

引用

页码：3048 / 3053

页数：6

共 59 条

[1] Abdelaal MY, 2000, J APPL POLYM SCI, V77, P3044, DOI 10.1002/1097-4628(20000929)77:14<3044::AID-APP30>3.0.CO
[2] 2-Q
[3] Successive ratio-derivative spectra as a new spectrophotometric method for the analysis of ternary mixtures
Afkhami, A
Bahram, M
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2005, 61 (05) : 869 - 877
[4] Mean centering of ratio kinetic profiles as a novel spectrophotometric method for the simultaneous kinetic analysis of binary mixtures
Afkhami, A
Bahram, M
[J]. ANALYTICA CHIMICA ACTA, 2004, 526 (02) : 211 - 218
[5] H-point standard addition method for simultaneous spectrophotometric determination of Co(II) and Ni(II) by 1-(2-pyridylazo)2-naphthol in micellar media
Afkhami, A
Bahram, M
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2004, 60 (1-2) : 181 - 186
[6] Determination of zinc (II) in pharmaceuticals based on a flow-through bulk optode
Albero, MI
Ortuño, JA
García, MS
Sánchez-Pedreño, C
Expósito, R
[J]. JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS, 2002, 29 (05) : 779 - 786
[7] Poly(vinyl chloride)-membrane ion-selective bulk optode based on 1,10-dibenzyl-1,10-diaza-18-crown-6 and 1-(2-pyridylazo)-2-naphthol for Cu2+ and Pb2+ ions
Alizadeh, N
Moemeni, A
Shamsipur, M
[J]. ANALYTICA CHIMICA ACTA, 2002, 464 (02) : 187 - 196
[8] Continuous flow-through solid phase spectrophotometric determination of trace amounts of zinc
Ayora-Cañada, MJ
Pascual-Reguera, MI
Molina-Díaz, A
[J]. ANALYTICA CHIMICA ACTA, 1998, 375 (1-2) : 71 - 80
[9] SYNTHESIS AND CHARACTERIZATION OF RARE-EARTH METAL-CONTAINING POLYMERS .1. FLUORESCENT PROPERTIES OF IONOMERS CONTAINING DY3+, ER3+, EU3+, AND SM3+
BANKS, E
OKAMOTO, Y
UEBA, Y
[J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1980, 25 (03) : 359 - 368
[10] Inelastic neutron scattering and infrared spectroscopic study of furan adsorption on alkali-metal cation-exchanged faujasites
Beta, IA
Herve, J
Geidel, E
Böhlig, H
Hunger, B
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2001, 57 (07) : 1393 - 1403

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