Synthesis of an amino phosphinodiselenoic acid ester and β-amino diselenides employing P2Se5

被引：2

作者：

Kumar, L. Roopesh ^{[1
]}

Sagar, N. R. ^{[1
]}

Divya, K. ^{[1
]}

Madhu, C. ^{[1
]}

Sureshbabu, Vommina V. ^{[1
]}

机构：

[1] Bangalore Univ, Dept Studies Chem, Peptide Res Lab, Bangalore 560056, Karnataka, India

来源：

NEW JOURNAL OF CHEMISTRY | 2020年 / 44卷 / 18期

关键词：

ONE-POT; ENANTIOSELECTIVE ADDITION; UNSYMMETRICAL SELENOUREAS; CONVENIENT SYNTHESIS; PRIMARY SELENOAMIDES; EFFICIENT SYNTHESIS; SELENATING REAGENT; DERIVATIVES; SELENOCARBOXAMIDES; CONVERSION;

D O I：

10.1039/d0nj00012d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of a new class of amino phosphinodiselenoic acid ester and beta-amino diselenides is conducted by employing a reaction between N-beta-protected aminoalkyl iodide and phosphorus pentaselenide (P2Se5) has been described. In the presence of protic solvents, amino phosphinodiselenoic acid esters were found to be the major products, whereas beta-amino diselenides were formed exclusively when the reaction was carried out in polar aprotic solvents.

引用

页码：7261 / 7264

页数：4

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