In situ Raman and UV-vis spectroscopic studies of polypyrrole and poly(pyrrole-2,6-dimethyl-β-cyclodextrin)

被引：87
作者：
Arjomandi, Jalal [1 ]
Shah, Anwar-ul-Haq Ali [2 ]
Bilal, Salma [3 ]
Hung Van Hoang [4 ]
Holze, Rudolf [5 ]
机构：
[1] Buali Sina Univ, Fac Chem, Hamadan 6517838683, Iran
[2] Abdul Wali Khan Univ Mardan, Dept Chem, Peshawar, Pakistan
[3] Univ Peshawar, Natl Ctr Excellence Phys Chem, Peshawar, Pakistan
[4] Hanoi Natl Univ Educ, Fac Chem, Hanoi, Vietnam
[5] Tech Univ Chemnitz, Inst Chem, D-09111 Chemnitz, Germany
来源：
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2011年 / 78卷 / 01期
关键词：
Spectroelectrochemistry; beta-Dimethyl cyclodextrin; Polypyrrole; Conducting polymer; Electropolymerization; HOST-GUEST COMPLEXATION; CONDUCTING POLYPYRROLE; REDOX REACTIONS; SERS SPECTRA; SPECTROELECTROCHEMISTRY; POLYANILINE; COMPOSITES; RESONANCE; ELECTROSYNTHESIS; POLYMERIZATION;
D O I：
10.1016/j.saa.2009.12.026
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
Polypyrrole (PPy) and poly(pyrrole-2,6-dimethyl-beta-cyclodextrin) [P(Py-beta-DMCD)] films prepared by potential cycling in aqueous acidic solutions on indium tin oxide (ITO)-coated glass and gold electrodes were studied by in situ UV-vis and Raman spectroscopy. Characteristic UV-vis and Raman bands were identified and their dependencies on the electrode potential have been discussed. Spectroelectrochemical results reveal differences both in the position of the spectral bands and their potential dependence for PPy and P(Py-beta-DMCD) films indicating interactions between polymer chains and CDs during electropolymerization process. The films were also characterized by cyclic voltammetry and FT-IR spectroscopy. (C) 2009 Elsevier B.V. All rights reserved.
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页码：1 / 6
页数：6
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