The mechanism of the terahertz spectroscopy for oil shale detection

被引:33
作者
Zhan, Honglei [1 ,2 ,3 ]
Chen, Mengxi [2 ]
Zhao, Kun [1 ,2 ,3 ]
Li, Yizhang [2 ]
Miao, Xinyang [2 ]
Ye, Haimu [3 ]
Ma, Yue [2 ]
Hao, Shijie [3 ]
Li, Hongfang [3 ]
Yue, Wenzheng [1 ]
机构
[1] China Univ Petr, State Key Lab Petr Resources & Prospecting, Beijing 102249, Peoples R China
[2] China Univ Petr, Beijing Key Lab Opt Detect Technol Oil & Gas, Beijing 102249, Peoples R China
[3] China Univ Petr, Dept Mat Sci & Engn, Beijing 102249, Peoples R China
基金
北京市自然科学基金;
关键词
Oil shale; Terahertz spectroscopy; Aliphatic compounds; Kerogen; PYROLYSIS; MINERALS; BEHAVIOR; TIME;
D O I
10.1016/j.energy.2018.07.112
中图分类号
O414.1 [热力学];
学科分类号
摘要
Terahertz time domain spectroscopy (THz-TDS) can directly detect oil shales. The absorption coefficient is related to the oil content in the rock. This value can be compared across regions to measuring the oil content in the oil shale. Here we studied three regions and included scanning electron microscope (SEM) and thermogravimetric analysis (TGA) to verify the amount of kerogen within oil shale prior to the constitution of the mineral matrix via the THz response. Aromatic and the aliphatic compounds contribute to the absorption of shales in the THz range due to the relatively high intramolecular interactions this reveals the mechanism of THz radiation penetration through shales as reported in previous reports. The differences in quantum structure of a molecule between organic and inorganic materials suggest that THz-TDS can be applied to geophysical prospecting and improve the effectiveness of the detection of organics in oil shale. (C) 2018 Elsevier Ltd. All rights reserved.
引用
收藏
页码:46 / 51
页数:6
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