Uniform nonspherical colloidal particles with tunable shapes

被引:223
作者
Kim, Jin-Woong
Larsen, Ryan J.
Weitz, David A. [1 ]
机构
[1] Harvard Univ, Sch Engn & Appl Sci, Cambridge, MA 02138 USA
[2] Harvard Univ, Dept Phys, Cambridge, MA 02138 USA
[3] Amore Pacific R&D Ctr, Yongin 446729, Gyeonggi Do, South Korea
关键词
D O I
10.1002/adma.200602345
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A framework for large-scale synthesis of a variety of uniform nonspherical particle types (see figure) is introduced. The technique involves controlling the directionality of phase separations in the seeded-polymerization technique by manipulating the crosslinking density gradients of the dimer seed particles, thus allowing the obtainment of novel nonspherical particle shapes and the production of sufficient quantities to characterize their bulk properties.
引用
收藏
页码:2005 / +
页数:6
相关论文
共 37 条
  • [1] BARRET KEJ, 1975, DISPRESION POLYM ORG
  • [2] Continuous-flow lithography for high-throughput microparticle synthesis
    Dendukuri, D
    Pregibon, DC
    Collins, J
    Hatton, TA
    Doyle, PS
    [J]. NATURE MATERIALS, 2006, 5 (05) : 365 - 369
  • [3] Improving the density of jammed disordered packings using ellipsoids
    Donev, A
    Cisse, I
    Sachs, D
    Variano, E
    Stillinger, FH
    Connelly, R
    Torquato, S
    Chaikin, PM
    [J]. SCIENCE, 2004, 303 (5660) : 990 - 993
  • [4] Effects of cross-linking on the morphology of structured latex particles .1. Theoretical considerations
    Durant, YG
    Sundberg, DC
    [J]. MACROMOLECULES, 1996, 29 (26) : 8466 - 8472
  • [5] Flory P. J, 1953, PRINCIPLES POLYM CHE
  • [6] Some assembly required
    Glotzer, SC
    [J]. SCIENCE, 2004, 306 (5695) : 419 - 420
  • [7] Heterodimers of nanoparticles: Formation at a liquid-liquid interface and particle-specific surface modification by functional molecules
    Gu, HW
    Yang, ZM
    Gao, JH
    Chang, CK
    Xu, B
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (01) : 34 - 35
  • [8] Synthesis of colloidal silica dumbbells
    Johnson, PM
    van Kats, CM
    van Blaaderen, A
    [J]. LANGMUIR, 2005, 21 (24) : 11510 - 11517
  • [9] A snowman-like array of colloidal dimers for antireflecting surfaces
    Koo, HY
    Yi, DK
    Yoo, SJ
    Kim, DY
    [J]. ADVANCED MATERIALS, 2004, 16 (03) : 274 - +
  • [10] Monodispersed ZnS dimers, trimers, and tetramers for lower symmetry photonic crystal lattices
    Liddell, CM
    Summers, CJ
    [J]. ADVANCED MATERIALS, 2003, 15 (20) : 1715 - +