Size-exclusion chromatography of metal nanoparticles and quantum dots

被引:80
作者
Pitkanen, Leena [1 ]
Striegel, Andre M. [1 ]
机构
[1] NIST, Div Chem Sci, 100 Bur Dr,MS 8392, Gaithersburg, MD 20899 USA
关键词
Size-exclusion chromatography; Characterization; Metal nanoparticles; Quantum dots; FIELD-FLOW FRACTIONATION; AU/PD CORE/SHELL NANOPARTICLES; HYDRODYNAMIC CHROMATOGRAPHY; AU NANOPARTICLES; SILVER NANOPARTICLES; GOLD NANOPARTICLES; OPTICAL-PROPERTIES; SEPARATION; PARTICLES; CDSE;
D O I
10.1016/j.trac.2015.06.013
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
This review presents an overview of size-exclusion chromatographic separation and characterization of noble metal nanoparticles (NPs) and quantum dots (QDs) over the past 25 years. The properties of NPs and QDs that originate from quantum and surface effects are size dependent; to investigate these properties, a separation technique such as size-exclusion chromatography (SEC) is often needed to obtain narrow distribution NP populations that are also separated from the unreacted starting materials. Information on the size distributions and optical properties of NPs has been obtained by coupling SEC to detection methods such as ultraviolet visible and/or fluorescence spectroscopy. Problems associated with the sorption of NPs and QDs onto various SEC stationary phases, using both aqueous and organic eluents, are also discussed. Published by Elsevier B.V.
引用
收藏
页码:311 / 320
页数:10
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