On measurement of thermal diffusion coefficients in multicomponent mixtures

We investigate the steady-state separation of the individual components of an incompressible multicomponent liquid mixture in a narrow two-dimensional thermogravitational column. Analytic working equations for measuring thermal diffusion coefficients analogous to the existing equations for a binary mixture are derived. Similar to the binary results, we find that when compositional variation has negligible effect on fluid density and vertical diffusive flux can be ignored, molecular diffusion does not affect steady-state separation. However, when compositional effects on density are taken into account, molecular diffusion does affect the bulk convective flow and the steady-state separation of the components. There may be also two distinct trends in the velocity and separation profiles. With one or more negative thermal diffusion coefficients, there may be more than one convection cell resulting in oscillatory behavior of separation. The working equations presented can be used to measure thermal diffusion coefficients of multicomponent mixtures. Such measurements have not yet been reported in the literature. (C) 2005 American Institute of Physics.