The importance of the CTAB surfactant on the colloidal seed-mediated synthesis of gold nanorods

被引:371
作者
Smith, Danielle K. [1 ]
Korgel, Brian A. [1 ]
机构
[1] Univ Texas Austin, Dept Chem Engn, Texas Mat Inst, Ctr Nano & Mol Sci & Technol, Austin, TX 78712 USA
基金
美国国家卫生研究院;
关键词
D O I
10.1021/la703625a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Gold nanorods were synthesized by the colloidal seed-mediated, surfactant-assisted approach [Gou et at., Chem. Mater. 2005,17,3668-3672] using CTAB (hexadecylcetyltrimethylammonium bromide) obtained from ten different suppliers. The yield of gold nanorods depended strongly on the CTAB used: with the same recipe, three of the CTABs did not yield nanorods and produced only spherical gold particles, whereas the other CTABs yielded nanorods with nearly 100% yield. These results suggest that an impurity in the CTAB is very important for nanorod formation.
引用
收藏
页码:644 / 649
页数:6
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共 48 条
[1]   Chemistry and properties of nanocrystals of different shapes [J].
Burda, C ;
Chen, XB ;
Narayanan, R ;
El-Sayed, MA .
CHEMICAL REVIEWS, 2005, 105 (04) :1025-1102
[2]   An improved synthesis of high-aspect-ratio gold nanorods [J].
Busbee, BD ;
Obare, SO ;
Murphy, CJ .
ADVANCED MATERIALS, 2003, 15 (05) :414-+
[3]   Gold nanoparticles are taken up by human cells but do not cause acute cytotoxicity [J].
Connor, EE ;
Mwamuka, J ;
Gole, A ;
Murphy, CJ ;
Wyatt, MD .
SMALL, 2005, 1 (03) :325-327
[4]   Effect of cationic liposome composition on in vitro cytotoxicity and protective effect on carried DNA [J].
Cortesi, R ;
Esposito, E ;
Menegatti, E ;
Gambari, R ;
Nastruzzi, C .
INTERNATIONAL JOURNAL OF PHARMACEUTICS, 1996, 139 (1-2) :69-78
[5]   Gold nanorods coated with multilayer polyelectrolyte as contrast agents for multimodal imaging [J].
Ding, Hong ;
Yong, Ken-Tye ;
Roy, Indrajit ;
Pudavar, Haridas E. ;
Law, Wing Cheung ;
Bergey, Earl J. ;
Prasad, Paras N. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (34) :12552-12557
[6]   Two-photon luminescence imaging of cancer cells using molecularly targeted gold nanorods [J].
Durr, Nicholas J. ;
Larson, Timothy ;
Smith, Danielle K. ;
Korgel, Brian A. ;
Sokolov, Konstantin ;
Ben-Yakar, Adela .
NANO LETTERS, 2007, 7 (04) :941-945
[7]   Dependence of the gold nanorod aspect ratio on the nature of the directing surfactant in aqueous solution [J].
Gao, JX ;
Bender, CM ;
Murphy, CJ .
LANGMUIR, 2003, 19 (21) :9065-9070
[8]   Biotin-streptavidin-induced aggregation of gold nanorods: Tuning rod-rod orientation [J].
Gole, A ;
Murphy, CJ .
LANGMUIR, 2005, 21 (23) :10756-10762
[9]   Polyelectrolyte-coated gold nanorods: Synthesis, characterization and immobilization [J].
Gole, A ;
Murphy, CJ .
CHEMISTRY OF MATERIALS, 2005, 17 (06) :1325-1330
[10]   Seed-mediated synthesis of gold nanorods: Role of the size and nature of the seed [J].
Gole, A ;
Murphy, CJ .
CHEMISTRY OF MATERIALS, 2004, 16 (19) :3633-3640