Insertion of dichlorocarbene into C-B bond of borinates under liquid-liquid phase transfer catalysis conditions: A convenient preparation of unsymmetrical ketones

被引：0

作者：

Huang, SW ^{[1
]}

Guo, F

Shan, ZX

Zhao, DJ

机构：

[1] Wuhan Univ, Dept Chem, Wuhan 430072, Hubei, Peoples R China

[2] Hubei Polytech Univ, Dept Chem Engn, Wuhan 430068, Hubei, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2001年 / 19卷 / 02期

关键词：

dichlorocarbene; insertion; borinate; phase transfer catalysis; unsymmetrical ketone;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Unsymmetrical ketones were conveniently prepared from the unsymmetrical diorganyl borinates via the insertion of dichlorocarbene into C-B bond under Liquid-liquid phase transfer catalysts conditions and oxidation with alkaline hydrogen peroxide in 35-67% yields.

引用

页码：202 / 204

页数：3