Insertion of dichlorocarbene into C-B bond of borinates under liquid-liquid phase transfer catalysis conditions: A convenient preparation of unsymmetrical ketones

被引：0

作者：

Huang, SW ^{[1
]}

Guo, F

Shan, ZX

Zhao, DJ

机构：

[1] Wuhan Univ, Dept Chem, Wuhan 430072, Hubei, Peoples R China

[2] Hubei Polytech Univ, Dept Chem Engn, Wuhan 430068, Hubei, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2001年 / 19卷 / 02期

关键词：

dichlorocarbene; insertion; borinate; phase transfer catalysis; unsymmetrical ketone;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Unsymmetrical ketones were conveniently prepared from the unsymmetrical diorganyl borinates via the insertion of dichlorocarbene into C-B bond under Liquid-liquid phase transfer catalysts conditions and oxidation with alkaline hydrogen peroxide in 35-67% yields.

引用

页码：202 / 204

页数：3

共 13 条

[1] AKIMOTO L, 1981, SYNTHETIC COMMUN, V11, P475
[2] REACTION OF DICHLOROCARBENE WITH 1,2-DIHYDRO 1,2-LAMBDA-3-AZAPHOSPHININE-BORANES - DICHLOROCYCLOPROPANATION AND INSERTION INTO BORON HYDROGEN-BOND
BEDEL, C
FOUCAUD, A
[J]. TETRAHEDRON LETTERS, 1993, 34 (02) : 311 - 314
[3] BOUVEAULT L, 1906, B SOC CHIM FR, V35, P648
[4] REACTION OF CARBON MONOXIDE AT ATMOSPHERIC PRESSURE WITH TRIALKYLBORANES IN PRESENCE OF WATER . A CONVENIENT SYNTHESIS OF DIALKYLKETONES VIA HYDROBORATION
BROWN, HC
RATHKE, MW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (11) : 2738 - &
[5] BASE-INDUCED REACTION OF BORINIC ACID ESTERS WITH ALPHA-ALPHA-DICHLOROMETHYL METHYL-ETHER - NEW ROUTE TO KETONES VIA HYDROBORATION
CARLSON, BA
BROWN, HC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (20) : 6876 - 6877
[6] KE T, 1995, J WUHAN U NAT SCI ED, V41, P702
[7] MIKHAILOV BM, 1959, ZH OBSHCH KHIM, P3310
[8] A SIMPLE SYNTHESIS OF DIALKYLKETONES FROM ALKENES VIA HYDROBORATION-CARBENOIDATION
NARAYANA, C
PERIASAMY, M
[J]. TETRAHEDRON LETTERS, 1985, 26 (51) : 6361 - 6364
[9] CHEMISTRY OF ORGANOBORATES .1. NEW, HIGH-YIELD KETONE SYNTHESES BY REACTION OF TRIALKYCYANOBORATES WITH ACYLATING AGENTS OR N-PHENYLBENZIMIDOYL CHLORIDE
PELTER, A
SMITH, K
HUTCHINGS, MG
ROWE, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1975, (02): : 129 - 138
[10] SYNTHESIS OF KETONES AND TERTIARY ALCOHOLS FROM TRIALKYLBORANES - USE OF LITHIUM TRIS(PHENYLTHIO)METHANIDE
PELTER, A
RAO, JM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (21) : 1149 - 1150

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