Selective gas sorption within a dynamic metal-organic framework

被引：117

作者：

Chen, Banglin ^{[1
]}

Ma, Shengqian

Hurtado, Eric J.

Lobkovsky, Emil B.

Liang, Chengdu

Zhu, Haoguo

Dai, Sheng

机构：

[1] Univ Texas Pan Amer, Dept Chem, Edinburg, TX 78541 USA

[2] Miami Univ, Dept Chem & Biochem, Oxford, OH 45056 USA

[3] Cornell Univ, Baker Lab, Dept Chem & Chem Biol, Ithaca, NY 14853 USA

[4] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Div Chem Sci, Oak Ridge, TN 37831 USA

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 21期

关键词：

D O I：

10.1021/ic7013573

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A microporous metal-organic framework 1 Co(NDC)(4,4'-Bipy)(0.5).G(x), (NDC = 2,6-naphthaleriedicarboxylate; 4,4'-Bipy = 4,4'-bipyridine; G = guest molecules) was synthesized and structurally characterized of a doubly interpenetrated primitive cubic net. To make use of the framework flexibility, 1 was activated at temperatures of 150 and 200 degrees C to form 1a and 1b, respectively, exhibiting highly selective sorption behaviors of hydrogen over nitrogen-gas molecules.

引用

页码：8705 / 8709

页数：5

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