Caesium nickel(II) trichloride, CsNiCl3, and tricaesium nickel(II) pentachloride, Cs3NiCl5

被引：11

作者：

Sassmannshausen, M ^{[1
]}

Lutz, HD ^{[1
]}

机构：

[1] Univ Gesamthsch Siegen, D-57068 Siegen, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270197019598

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

There are two congruently melting compounds in the CsCl-NiCl2 system: orange CsNiCl3 (absorption maximum 466 nm) and turquoise Cs3NiCl5 (654 nm). The different colours are caused by the different coordination polyhedra of the nickel(II) ions. In Cs3NiCl5, which crystallizes in the tetragonal space group I4/mcm, there are isolated NiCl42- tetrahedra, whereas in CsNiCl3, which crystallizes in the hexagonal space group P6(3)/mmc, the Ni2+ ions are octahedrally coordinated. These octahedra run parallel to [001] and share triangular faces.

引用

页码：704 / 706

页数：3

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