Suppression of the polysulfide-shuttle behavior in Li-S batteries through the development of a facile functional group on the polypropylene separator

被引:68
|
作者
Yu, Xingwen
Joseph, Jorphin
Manthiram, Arumugam [1 ]
机构
[1] Univ Texas Austin, Mat Sci & Engn Program, Austin, TX 78712 USA
关键词
LITHIUM-SULFUR BATTERIES; CARBON COMPOSITES; PERFORMANCE; CATHODE; ELECTROCHEMISTRY; ELECTROLYTE; CHALLENGES; PROGRESS;
D O I
10.1039/c6mh00043f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Towards suppressing the polysulfide-shuttle behavior in lithium-sulfur (Li-S) batteries, a facile functional group has strategically been developed on the commercial polypropylene (PP) battery separator through a sequence of hydroxylating, grafting, and hydrolyzing processes. The Li-S cells with the modified PP separator shows significantly enhanced cyclability.
引用
收藏
页码:314 / 319
页数:6
相关论文
共 50 条
  • [1] Stabilizing polysulfide-shuttle in a Li-S battery using transition metal carbide nanostructures
    Al Salem, Hesham
    Chitturi, Venkateswara Rao
    Babu, Ganguli
    Santana, Juan A.
    Gopalakrishnan, Deepesh
    Arava, Leela Mohana Reddy
    RSC ADVANCES, 2016, 6 (111) : 110301 - 110306
  • [2] Functional Design of Separator for Li-S Batteries
    Sun, Hao
    Song, Chengwei
    Pang, Yuepeng
    Zheng, Shiyou
    PROGRESS IN CHEMISTRY, 2020, 32 (09) : 1402 - 1411
  • [3] Electrocatalytic polysulfide transformation for suppressing the shuttle effect of Li-S batteries
    Na, Tiancheng
    Liu, Yang
    Li, Xiangcun
    Zheng, Wenji
    Dai, Yan
    Yan, Zhijun
    Kou, Wei
    He, Gaohong
    APPLIED SURFACE SCIENCE, 2020, 528
  • [4] Crosslinked disulfide polymers suppress polysulfide shuttle in Li-S batteries
    Preefer, Molleigh
    Oschmann, Bernd
    Hawker, Craig
    Seshadri, Ram
    Wudl, Fred
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
  • [5] Bifunctional separator as a polysulfide mediator for highly stable Li-S batteries
    Abbas, Syed Ali
    Ibrahem, Mohammad Aziz
    Hu, Lung-Hao
    Lin, Chia-Nan
    Fang, Jason
    Boopathi, Karunakara Moorthy
    Wang, Pen-Cheng
    Li, Lain-Jong
    Chu, Chih-Wei
    JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (24) : 9661 - 9669
  • [6] Empowering polypropylene separator with enhanced polysulfide adsorption and reutilization ability for high-performance Li-S batteries
    Xiao, Zhen
    Li, Yao
    Zhang, Wenkui
    Huang, Hui
    Gan, Yongping
    Zhang, Jun
    Liang, Chu
    Mao, Qinzhong
    Liao, Peng
    Jin, Yanxian
    Xia, Yang
    MATERIALS RESEARCH BULLETIN, 2021, 134
  • [7] Recent development of polysulfide barriers for Li-S batteries
    Xu Zhao
    You Hui-hui
    Zhang Lei
    Yang Quan-hong
    NEW CARBON MATERIALS, 2017, 32 (02) : 97 - 105
  • [8] Simultaneous Suppression of Shuttle Effect and Lithium Dendrite Growth by Lightweight Bifunctional Separator for Li-S Batteries
    Kim, Seoa
    Lim, Won-Gwang
    Cho, Ara
    Jeong, Jooyoung
    Jo, Changshin
    Kang, DongGyu
    Han, Seung Min
    Han, Jeong Woo
    Lee, Jinwoo
    ACS APPLIED ENERGY MATERIALS, 2020, 3 (03): : 2643 - 2652
  • [9] Modified Separator Performing Dual Physical/Chemical Roles to Inhibit Polysulfide Shuttle Resulting in Ultrastable Li-S Batteries
    Abbas, Syed Ali
    Ding, Jiang
    Wu, Sheng Hui
    Fang, Jason
    Boopathi, Karunakara Moorthy
    Mohapatra, Anisha
    Lee, Li Wei
    Wang, Pen-Cheng
    Chang, Chien-Cheng
    Chu, Chih Wei
    ACS NANO, 2017, 11 (12) : 12436 - 12445
  • [10] Electromagnetic confinement of polysulfides for shuttle suppression of Li-S batteries
    Zhou, Yingke (zhouyk@wust.edu.cn), 1600, Elsevier B.V. (503):