γ-DNA induced turbulent drag reduction and its characteristics

被引:42
作者
Lim, ST
Choi, HJ [1 ]
Lee, SY
So, JS
Chan, CK
机构
[1] Inha Univ, Dept Polymer Sci & Engn, Inchon 402751, South Korea
[2] Inha Univ, Dept Biol Engn, Inchon 402751, South Korea
[3] Inha Univ, Ctr Adv Bioseparat Technol, Inchon 402751, South Korea
[4] Acad Sinica, Inst Phys, Taipei 115, Taiwan
关键词
D O I
10.1021/ma025964k
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Turbulent drag reduction (DR) induced by monodispersed high molecular weight lambda-DNA in a buffer solution under a turbulent flow was investigated using a rotating disk apparatus. The DR efficiency was maintained over time due to the durability of the lambda-DNA in a moderate turbulent shear flow, and this behavior was compared to a water-soluble linear flexible long chain polyacrylamide (PAAM). To investigate the mechanical degradation mechanism of lambda-DNA, the maximum drag reducing rotation speed (rpm) of the disk was examined by increasing the rotation speed using two different modes to increase the rpm: a continuous and stepwise mode. The mechanical degradation of lambda-DNA with a high turbulent flow was analyzed using an electrophoresis method, which indicated a midpoint scission of the long chain molecules. The DR efficiency at different rotation speeds and results of a long-term experiment also supported the half-length degradation of lambda-DNA and strong resistance of the helically stranded lambda-DNA structure in a turbulent flow compared to its water-soluble flexible counterpart.
引用
收藏
页码:5348 / 5354
页数:7
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