Synthesis and crystal structures of coordination polymers, networks and complexes of an adamantane shaped phosphorus-nitrogen cage ligand and cuprous chloride

被引：4
作者：
Leser, Eric D. [1 ]
Noll, Bruce C. [2 ]
Sommer, Roger D. [1 ]
机构：
[1] Depaul Univ, Dept Chem, Chicago, IL 60614 USA
[2] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA
来源：
POLYHEDRON | 2010年 / 29卷 / 09期
基金：
美国国家科学基金会;
关键词：
Coordination polymer; Copper(I); Phosphorus-nitrogen ligand; CLOSO-TETRAPHOSPHORUS HEXAKIS(METHYLIMIDE); RING-OPENING POLYMERIZATION; COPPER(I) CYANIDE NETWORKS; METAL-ORGANIC FRAMEWORK; TERTIARY PHOSPHINE; LUMINESCENCE BEHAVIOR; ARSINE COMPLEXES; DERIVATIVES; CHEMISTRY; SILVER(I);
D O I：
10.1016/j.poly.2010.03.019
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of cuprous chloride with the phosphorus-nitrogen cage ligand 2,4,6,8,9,10-hexamethyl-2,4,6,8,9,10-hexaaza-1,3,5,7-tetraphosphaadamantane, P-4(NCH3)(6), in acetonitrile form distinct solids depending on the ligand-to-metal ratio. Three structurally characterized compounds include: a solvated 3-D network of formula [P-4(NCH3)(6)](2)(CuCl)(3)(CH3CN)(2); a "ladder-type" Polymer {[mu(2)-P-4(NCH3)(6)](2) (CuCl)(2))}; and a monomeric complex [P-4(NCH3)(6)](2)CuCl. Thermal decomposition of the solvated network results in formation of two more materials [P-4(NCH3)(6)](2)(CuCl)(3), and [P-4(NCH3)(6)](CuCl)(2) that are not isolated from solution reactions. The variety of products isolated based solely on ligand-to-metal ratio suggest that this system participates in solution equilibria common to many phosphorus(III) ligands and multiple solubility equilibria. (C) 2010 Elsevier Ltd. All rights reserved.
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页码：2053 / 2060
页数：8
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