Synthesis and crystal structures of coordination polymers, networks and complexes of an adamantane shaped phosphorus-nitrogen cage ligand and cuprous chloride

被引:4
|
作者
Leser, Eric D. [1 ]
Noll, Bruce C. [2 ]
Sommer, Roger D. [1 ]
机构
[1] Depaul Univ, Dept Chem, Chicago, IL 60614 USA
[2] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA
基金
美国国家科学基金会;
关键词
Coordination polymer; Copper(I); Phosphorus-nitrogen ligand; CLOSO-TETRAPHOSPHORUS HEXAKIS(METHYLIMIDE); RING-OPENING POLYMERIZATION; COPPER(I) CYANIDE NETWORKS; METAL-ORGANIC FRAMEWORK; TERTIARY PHOSPHINE; LUMINESCENCE BEHAVIOR; ARSINE COMPLEXES; DERIVATIVES; CHEMISTRY; SILVER(I);
D O I
10.1016/j.poly.2010.03.019
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reactions of cuprous chloride with the phosphorus-nitrogen cage ligand 2,4,6,8,9,10-hexamethyl-2,4,6,8,9,10-hexaaza-1,3,5,7-tetraphosphaadamantane, P-4(NCH3)(6), in acetonitrile form distinct solids depending on the ligand-to-metal ratio. Three structurally characterized compounds include: a solvated 3-D network of formula [P-4(NCH3)(6)](2)(CuCl)(3)(CH3CN)(2); a "ladder-type" Polymer {[mu(2)-P-4(NCH3)(6)](2) (CuCl)(2))}; and a monomeric complex [P-4(NCH3)(6)](2)CuCl. Thermal decomposition of the solvated network results in formation of two more materials [P-4(NCH3)(6)](2)(CuCl)(3), and [P-4(NCH3)(6)](CuCl)(2) that are not isolated from solution reactions. The variety of products isolated based solely on ligand-to-metal ratio suggest that this system participates in solution equilibria common to many phosphorus(III) ligands and multiple solubility equilibria. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2053 / 2060
页数:8
相关论文
共 37 条
  • [1] Synthesis, structures and physical properties of mixed-ligand coordination polymers based on a V-shaped dicarboxylic ligand
    Yang, Yan-Yan
    Lin, Zu-Jin
    Liu, Tao-Tao
    Liang, Jun
    Cao, Rong
    CRYSTENGCOMM, 2015, 17 (06): : 1381 - 1388
  • [2] Synthesis, structures, and properties of alkali and alkaline earth coordination polymers based on V-shaped ligand
    Cheng, P. -C.
    Tseng, F. -S.
    Yeh, C. -T.
    Chang, T. -G.
    Kao, C. -C.
    Lin, C. -H.
    Liu, W. -R.
    Chen, J. -S.
    Zima, V.
    CRYSTENGCOMM, 2012, 14 (20): : 6812 - 6822
  • [3] Synthesis, Crystal Structures and Characterization of Two Cadmium Coordination Polymers Based on a Bis(imidazole) Ligand
    Zhang Wei-Guo
    Gui Guang-Hua
    Jiao Cui-Huan
    Geng Jian-Chen
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2012, 28 (11) : 2494 - 2500
  • [4] Synthesis, crystal structures and photoluminescence studies of three mixed ligand silver(I) coordination polymers
    You-Tian Meng
    Ya-Jie Ruan
    Jin-Ping Mo
    Bao-Lin Liu
    Ai-Yin Wang
    Hong-Ping Xiao
    Transition Metal Chemistry, 2017, 42 : 285 - 291
  • [5] Synthesis and Crystal Structures of Two Coordination Polymers Based on a New N-Donor Aromatic Ligand
    Zhao, D.
    Ma, F. X.
    Zhang, R. H.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 59 (07) : 1678 - 1683
  • [6] Synthesis and Crystal Structures of Two Coordination Polymers Based on a New N-Donor Aromatic Ligand
    D. Zhao
    F. X. Ma
    R. H. Zhang
    Journal of Structural Chemistry, 2018, 59 : 1678 - 1683
  • [7] Coordination Polymers with Tris(4-Carboxyphenyl)-Phosphine Oxide as Ligand - Synthesis, Crystal Structures and Topological Investigations
    Schmiedel, Peter
    Krautscheid, Harald
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2012, 638 (11): : 1839 - 1848
  • [8] Crystal structures and magnetic properties of two Co(II) coordination polymers created via in situ ligand synthesis
    Zhao, Ying
    Dang, Li-Long
    Zhai, Zhi-Min
    Ma, Lu-Fang
    Wang, Li-Ya
    JOURNAL OF SOLID STATE CHEMISTRY, 2020, 290
  • [9] Synthesis, crystal structures and magnetic properties of three porous coordination polymers based on a semirigid tripodal carboxylate ligand
    Sun, Yanchun
    Yin, Mingdong
    Chen, Shiqiang
    Zhao, Jianshe
    TRANSITION METAL CHEMISTRY, 2021, 46 (02) : 167 - 175
  • [10] Syntheses, Crystal Structures, and Magnetic Properties of Two Mn(II) Coordination Polymers Based on the 5-Aminotetrazole Ligand: Effect of Sources of Ligand on Construction of Topological Networks
    Wang, Tian-Wei
    Liu, Dong-Sheng
    Huang, Chang-Cang
    Sui, Yan
    Huang, Xi-He
    Chen, Jian-Zhong
    You, Xiao-Zeng
    CRYSTAL GROWTH & DESIGN, 2010, 10 (08) : 3429 - 3435