Aqueous-phase hydrogenation of alkenes and arenes: The growing role of nano scale catalysts

被引：26

作者：

Bulut, Safak ^{[1
]}

Fei, Zhaofu ^{[1
]}

Siankevich, Sviatlana ^{[1
]}

Zhang, Jiaguang ^{[2
]}

Yan, Ning ^{[2
]}

Dyson, Paul J. ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

[2] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 117585, Singapore

来源：

CATALYSIS TODAY | 2015年 / 247卷

基金：

瑞士国家科学基金会;

关键词：

Biphasic catalysis; Hydrogenation; Aqueous-phase hydrogenation; Polymer stabilizers; Nanocatalysts; Nanoparticles; DENDRIMER-ENCAPSULATED PD; SUZUKI COUPLING REACTIONS; B AMORPHOUS ALLOY; SELECTIVE HYDROGENATION; IONIC LIQUIDS; PALLADIUM NANOPARTICLES; EFFICIENT HYDROGENATION; HETEROGENEOUS CATALYSIS; AEROBIC HYDROGENATION; BIMETALLIC CATALYSTS;

D O I：

10.1016/j.cattod.2014.09.002

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

In this article we highlight some of the recent developments in the aqueous-phase hydrogenation of alkenes and arenes. The traditional types of water-soluble catalysts applied in aqueous media are outlined together with recent trends towards the development of transition metal nanoparticle and nanocomposite catalysts. In addition, we describe some palladium nanoparticle catalysts that are stabilized by ionic polymers, which demonstrate superior activities in the aqueous-phase catalytic hydrogenation of styrene, used as a model substrate, compared to related palladium nanoparticles. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：96 / 103

页数：8

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